On symmetry breaking of dual polyhedra of non-crystallographic group H.

Acta Crystallogr A Found Adv

Département de Physique, Université de Montréal, Complexe des Sciences, 1375 Avenue Thérèse-Lavoie-Roux, Montréal, H2V 0B3, Québec, Canada.

Published: July 2021

The study of the polyhedra described in this paper is relevant to the icosahedral symmetry in the assembly of various spherical molecules, biomolecules and viruses. A symmetry-breaking mechanism is applied to the family of polytopes {\cal V}_{H_{3}}(\lambda) constructed for each type of dominant point λ. Here a polytope {\cal V}_{H_{3}}(\lambda) is considered as a dual of a {\cal D}_{H_{3}}(\lambda) polytope obtained from the action of the Coxeter group H on a single point \lambda\in{\bb R}^{3}. The H symmetry is reduced to the symmetry of its two-dimensional subgroups H, A × A and A that are used to examine the geometric structure of {\cal V}_{H_{3}}(\lambda) polytopes. The latter is presented as a stack of parallel circular/polygonal orbits known as the `pancake' structure of a polytope. Inserting more orbits into an orbit decomposition results in the extension of the {\cal V}_{H_{3}}(\lambda) structure into various nanotubes. Moreover, since a {\cal V}_{H_{3}}(\lambda) polytope may contain the orbits obtained by the action of H on the seed points (a, 0, 0), (0, b, 0) and (0, 0, c) within its structure, the stellations of flat-faced {\cal V}_{H_{3}}(\lambda) polytopes are constructed whenever the radii of such orbits are appropriately scaled. Finally, since the fullerene C has the dodecahedral structure of {\cal V}_{H_{3}}(a,0,0), the construction of the smallest fullerenes C, C, C, C together with the nanotubes C, C is presented.

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http://dx.doi.org/10.1107/S2053273321002254DOI Listing

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