AI Article Synopsis
- The study describes the isolation and analysis of a stable Nickel dichloride complex that uses a specific ligand called a tetradentate pyridinophane.
- When this complex is exposed to light, it efficiently reacts to eliminate chlorine atoms, whether in a liquid solution or in a solid form.
- The Nickel chlorine species created can be restored by reacting it with another chemical, PhICl.
Article Abstract
Herein we report the isolation, characterization, and photoreactivity of a stable Ni dichloride complex supported by a tetradentate pyridinophane N-donor ligand. Upon irradiation, this complex undergoes an efficient photoreductive chlorine elimination reaction, both in solution and the solid-state. Subsequently, the NiCl species can be regenerated via a reaction with PhICl.
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| http://dx.doi.org/10.1039/d1cc02114a | DOI Listing |
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