Rigidity and Superfast Signal Propagation in Fluids and Solids in Non-Equilibrium Steady States.

J Phys Chem B

Institute for Physical Science and Technology, University of Maryland, College Park, Maryland 20742, United States.

Published: July 2021

In the 1980s, it was theoretically predicted that correlations of various observables in a fluid in a non-equilibrium steady state (NESS) are extraordinarily long-ranged, extending, in a well-defined sense, over the size of the system. This is to be contrasted with correlations in an equilibrium fluid, whose range is typically just a few particle diameters. These NESS correlations were later confirmed by numerous experimental studies. Unlike long-ranged correlations at critical points, these correlations are generic in the sense that they exist for any temperature as long as the system is in a NESS. In equilibrium systems, generic long-ranged correlations are caused by spontaneously broken continuous symmetries and are associated with a generalized rigidity, which in turn leads to a new propagating excitation or mode. For example, in a solid, spatial rigidity leads to transverse sound waves, while, in a superfluid, phase rigidity leads to temperature waves known as second sound at finite temperatures and phonons at zero temperature. More generally, long-ranged spatial correlations imply rigidity irrespective of their physical origin. This implies that a fluid in a NESS should also display a type of rigidity and related anomalous transport behavior. Here we show that this is indeed the case. For the particular case of a simple fluid in a constant temperature gradient, the anomalous transport behavior takes the form of a super-diffusive spread of a constant-pressure temperature perturbation. We also discuss the case of an elastic solid, where we predict a spread that is faster than ballistic.

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Source
http://dx.doi.org/10.1021/acs.jpcb.0c11283DOI Listing

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