Hydrothermal liquefaction (HTL) of biomass results in the formation of bio-oil, aqueous phase (HTL-AP), bio-char, and gaseous products. Safer disposal of HTL-AP is difficult on an industrial scale since it comprises low molecular acid compounds. This review provides a comprehensive note on the recent articles published on the effective usage of HTL-AP for the recovery of valuable compounds. Thermo-chemical and biological processes are the preferred techniques for the recovery of biofuel, platform chemicals from HTL-AP. From this review, it was evident that the composition of HTL-AP and product recovery are the integrated pathways, which depend on each other. Substitute as reaction medium in HTL process, growth medium for algae and microbes are the most common mode of reuse and recycle of HTL-AP. Future research is needed to depict the mechanism of HTL process when HTL-AP is used as a reaction medium on an industrial scale. Need to find a solution for the hindrance in commercializing HTL process and recovery of value-added compounds from HTL-AP from lab scale to industry level. Integrated pathways on reuse and HTL-AP recycle helps in reduced environmental concerns and sustainable production of bio-products.
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http://dx.doi.org/10.1016/j.chemosphere.2021.131248 | DOI Listing |
Light Sci Appl
January 2025
Key Laboratory for Special Functional Materials of Ministry of Education, National & Local Joint Engineering Research Center for High-efficiency Display and Lighting Technology, Henan University, 475004, Kaifeng, China.
Solution-processed quantum dot light-emitting diodes (QLEDs) hold great potential as competitive candidates for display and lighting applications. However, the serious energy disorder between the quantum dots (QDs) and hole transport layer (HTL) makes it challenging to achieve high-performance devices at lower voltage ranges. Here, we introduce "giant" fully alloy CdZnSe/ZnSeS core/shell QDs (size ~ 19 nm) as the emitting layer to build high-efficient and stable QLEDs.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
State Key Laboratory of Organic Electronics and Information Displays, Institute of Advanced Materials (IAM), School of Material Science and Engineering, Nanjing University of Posts and Telecommunications (NJUPT), 9 Wenyuan Rd., Nanjing 210023, China.
The performance of lead sulfide colloidal quantum dot (PbS-CQD) solar cells has long been hindered by interface defects in the transport layer. Traditionally, 1,2-ethanedithiol (EDT), used in solid-state ligand exchange, has been a common choice as the hole transport layer (HTL) in many PbS-CQD solar cells. However, the rapid reaction rate and chain length mismatch (shorter-chain EDT versus longer-chain oleic acid) during the ligand exchange process often introduce crack defects in the HTL film, resulting in an unexpected low performance.
View Article and Find Full Text PDFJ Microbiol Biotechnol
November 2024
Fatemah AlMalki, Biology Department, College of Science and Humanities- Al Quwaiiyah, Shaqra University, Al Quwaiiyah 19257, Saudi Arabia.
is a gram-negative, facultatively anaerobic bacterium typically found in the oropharynx and respiratory tract of humans. It is responsible for various infections, including head-and-neck infections, pericarditis, and abscesses of the deltoid, perirenal tissue, brain, and liver. Increasing antibiotic resistance requires urgent identification of novel drug targets to fight this bacterium.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Department of Materials Science and Engineering, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon, 34134, Republic of Korea.
Hole-transport layers (HTL) in perovskite solar cells (PSCs) with an n-i-p structure are commonly doped by bis(trifluoromethane)sulfonimide (TFSI) salts to enhance hole conduction. While lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) dopant is a widely used and effective dopant, it has significant limitations, including the need for additional solvents and additives, environmental sensitivity, unintended oxidation, and dopant migration, which can lead to lower stability of PSCs. A novel ionic liquid, 1-(2-methoxyethyl)-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (MMPyTFSI), is explored as an alternative dopant for 2,2',7,7'-tetrakis(N,N-di-p-methoxyphenylamino)-9,9'-spirobifluorene (spiro-OMeTAD).
View Article and Find Full Text PDFSci Rep
January 2025
Process and Energy Department, University of Technology of Delft, Leeghwaterstraat 39, 2628 CB, Delft, The Netherlands.
An urgent ecological issue is the threat posed by invasive species, which are becoming more widespread especially in Africa. These encroachments damage ecosystems, pose a threat to biodiversity, and outcompete local plants and animals. This article focuses on converting Acacia Mellifera from Namibia, commonly known as encroacher bush (EB) into high-quality drop-in intermediates for the chemical and transport industry via hydrothermal liquefaction (HTL).
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