Experimental investigation on gasification of cationic ion exchange resin used in nuclear power plants by supercritical water.

Spent ion exchange resins produced by nuclear power plants are radioactive organic waste. Until now, there is no satisfactory industrial treatment. Supercritical water gasification (SCWG) of cationic ion exchange resin (CIER) used in nuclear power plants was carried out in a batch reactor in this study. Results showed that the gasification efficiency increased with the growth of temperature (550-750 °C), addition of alkali homogeneous catalyst (KCO), proper ratio loading of catalyst to CIER (1:1), decrease of feed concentration (2-10 wt%) and extension of residence time (10-60 min). Carbon gasification efficiency was up to 97.98% with KCO added and 30 min at 750 °C in the batch reactor. The gaseous products mainly consist of H, CO, CO and CH. The GC-MS analysis showed that the organic component in liquid products was mainly composed of benzene, monocycle arenes, phenol group and polycyclic aromatic hydrocarbons. Based on the experimental results, the formation and gasification pathways of CIER in SCW were proposed.