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General synthesis of single-atom catalysts with high metal loading using graphene quantum dots. | LitMetric

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Article Abstract

Transition-metal single-atom catalysts present extraordinary activity per metal atomic site, but suffer from low metal-atom densities (typically less than 5 wt% or 1 at.%), which limits their overall catalytic performance. Here we report a general method for the synthesis of single-atom catalysts with high transition-metal-atom loadings of up to 40 wt% or 3.8 at.%, representing several-fold improvements compared to benchmarks in the literature. Graphene quantum dots, later interweaved into a carbon matrix, were used as a support, providing numerous anchoring sites and thus facilitating the generation of high densities of transition-metal atoms with sufficient spacing between the metal atoms to avoid aggregation. A significant increase in activity in electrochemical CO reduction (used as a representative reaction) was demonstrated on a Ni single-atom catalyst with increased Ni loading.

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http://dx.doi.org/10.1038/s41557-021-00734-xDOI Listing

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