Energetic metal-organic frameworks (EMOFs) are very promising as heat-resistant explosives, affording both thermal stability and energy properties. In this work, the self-assembly of high-energy nitrogen-rich linkers with nontoxic alkali-metal lithium/sodium leads to four new solvent-free EMOFs. Because of unparalleled decomposition temperature ( = 403 °C) and heats of detonation (3.475 kcal·g), a 3D Li(I)-EMOF can be considered to be a superheat-resistant explosive candidate.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acs.inorgchem.1c01658 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Climate friendly MOFs synthesis for drug delivery systems by integrating AI, intelligent manufacturing, and quantum solutions in industry 6.0 sustainable approach.
Toxicol Res (Camb)
February 2025
Department of chemistry, Emerson University Multan, Multan 60000, Pakistan.
Since the Industrial Revolution, ecological damage, ecosystem disruption, and climate change acceleration have frequently resulted from human advancement at the price of the environment. Due to the rise in illnesses, Industry 6.0 calls for a renewed dedication to sustainability with latest technologies.
View Article and Find Full Text PDFOptimizing adsorption and photocatalysis for tetracycline and sulfamethoxazole removal: the role of Ag and NH in Bi-MOF derivatives.
RSC Adv
January 2025
Department of Food Science and Biotechnology, Gachon University 1342 Seongnamdaero Sujeong-gu Seongnam-si 13120 Republic of Korea
This study focuses on the synthesis, characterization, and evaluation of the photocatalytic efficiency of bismuth-based metal-organic frameworks (Bi-MOFs) and their derivatives, specifically Ag/Bi-MOF and NH /Ag/Bi-MOF, in the degradation of tetracycline (TC) and sulfamethoxazole (SMX) under visible light irradiation. Bi-MOFs are promising photocatalysts due to their large surface area, tunable porosity, and unique electronic properties that are favorable for visible light absorption. In this study, Bi-MOFs were synthesized using a solvothermal method, with the incorporation of silver (Ag) and ammonium (NH ) ions to enhance their photocatalytic performance.
View Article and Find Full Text PDFRevealing the synergistic impacts of ZIF-8 and copper co-exposure on zebrafish behavior, tissue damage, and intestine microbial community.
Environ Res
January 2025
College of Environmental Science and Engineering and Key Laboratory of Environmental Biology and Pollution Control (Ministry of Education), Hunan University, Changsha 410082, PR China. Electronic address:
The application of metal-organic frameworks (MOFs) has garnered significant attention in contemporary research. However, the impacts of MOFs on aquatic environments remain largely unclear. This study revealed that the water stability of ZIF-8 is influenced by its concentration, with lower concentrations resulting in higher percentages of Zn release.
View Article and Find Full Text PDFToxicity mechanism of metal-organic framework HKUST-1 and its carbonized product to Tetradesmus obliquus: Physiological and transcriptomic analysis.
Comp Biochem Physiol C Toxicol Pharmacol
January 2025
School of Ecology and Environment, Collaborative Innovation Center of Recovery and Reconstruction of Degraded Ecosystem in Wanjiang Basin Co-founded by Anhui Province and Ministry of Education, Anhui Normal University, Wuhu 241002, China. Electronic address:
Metal-organic frameworks (MOFs) are emerging materials with unique structures and properties, which have been widely used in many fields due to their various advantages. However, compared with its popular application research, the ecological safety of MOFs has rarely been reported. In this paper, a biological model, the common freshwater green algae Tetradesmus obliquus (T.
View Article and Find Full Text PDFA hyaluronic acid modified copper-based metal-organic framework overcomes multidrug resistance via two-way redox dyshomeostasis under hypoxia.
Int J Biol Macromol
January 2025
College of Chemistry & Pharmacy, Northwest A&F University, Yangling, Shaanxi 712100, PR China. Electronic address:
Multidrug resistance (MDR) has become a major challenge in tumor chemotherapy, primarily associated with the overexpression of P-glycoprotein (P-gp). Inhibiting P-gp expression and function through redox dyshomeostasis has shown great potential for reversing MDR. Here, a nanometer system of copper-based metal-organic framework (HA-CuMOF@DOX) modified with hyaluronic acid (HA) was constructed to overcome MDR via two-way regulation of redox homeostasis under hypoxia.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!