Crystal structure of ethyl 2-(3-amino-5-oxo-2-tosyl-2,5-di-hydro-1-pyrazol-1-yl)acetate.

Acta Crystallogr E Crystallogr Commun

Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany.

Published: June 2021

In the title compound, CHNOS, the five-membered ring is essentially planar. The substituents at the nitro-gen atoms subtend a C-N-N-S torsion angle of -95.52 (6)°. The amino group forms an intra-molecular hydrogen bond to a sulfonyl oxygen atom; two inter-molecular hydrogen bonds from the amino group, to the other S=O group and to the oxo substituent, form a layer structure parallel to the plane. The structure determination confirms that the title compound is - rather than -alkyl-ated.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8183440PMC
http://dx.doi.org/10.1107/S2056989021004795DOI Listing

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