Nitrate pollution has become an environmental problem of global concern. One effective way for controlling the nitrate pollution of water is to identify the pollution source and reduce the input of nitrate. This study traces and quantifies the sources of nitrate contamination to groundwater and surface water in the northeastern suburbs of Beijing, where an emergency groundwater source zone is located. Nitrogen and oxygen stable isotope analysis, geospatial analysis techniques, principal component analysis, correlation analysis, and a Bayesian isotope mixing model were used to achieve our goals. The results show that the main sources of nitrate pollution in groundwater were manure and sewage (M&S) (42.6 %) > soil nitrogen (SN) (26.6 %) > in fertilizer and rain (NHF&R) (24.5 %) > fertilizer (NOF) (5.0 %) > in atmospheric deposition (NAD) (1.3 %), and main sources of nitrate in surface water were M&S (28.8 %) > SN (20.4 %) > NAD (19.8%) > NOF (16.5%) > NHF&R (14.5 %). Due to the high permeability of the aquifer in the study area, there was a strong hydraulic connection between groundwater and surface water. The discharge of treated wastewater (reclaimed water) into the mostly dried river channel in the study area might aggravate nitrate pollution in the groundwater.
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http://dx.doi.org/10.1080/10256016.2021.1937149 | DOI Listing |
Nat Commun
December 2024
School of Public Health, Key Lab of Public Health Safety of the Ministry of Education, Fudan University, Shanghai, China.
Fine particulate matter has been linked with acute coronary syndrome. Nevertheless, the key constituents remain unclear. Here, we conduct a nationwide case-crossover study in China during 2015-2021 to quantify the associations between fine particulate matter constituents (organic matter, black carbon, nitrate, sulfate, and ammonium) and acute coronary syndrome, and to identify the critical contributors.
View Article and Find Full Text PDFJACS Au
December 2024
State Key Laboratory of Fine Chemicals, School of Chemistry, Dalian University of Technology, Dalian 116024, China.
Nitroaromatics, as an important member and source of nitrogen-containing aromatics, is bringing enormous economic benefits in fields of pharmaceuticals, dyes, pesticides, functional materials, fertilizers, and explosives. Nonetheless, the notoriously polluting nitration industry, which suffers from excessive discharge of fumes and waste acids, poor functional group tolerance, and tremendous purification difficulty, renders mild, efficient, and environmentally friendly nitration a formidable challenge. Herein, we develop a visible-light-driven biocompatible arene C-H nitration strategy with good efficiency and regioselectivity, marvelous substrate applicability and functional group tolerance, and wide application in scale-up synthesis, total synthesis, and late-stage functionalization.
View Article and Find Full Text PDFWater Sci Technol
December 2024
Jiangsu Environmental Engineering Technology Co., Ltd, Nanjing 210000, China; Jiangsu Province Engineering Research Center of Synergistic Control of Pollution and Carbon Emissions in Key Industries, Nanjing 210000, China.
Moving bed biofilm reactors can purify urban domestic sewage through microbial biodegradation. High-throughput sequencing was used to study the response mechanism of the biofilm microbial community to temperature. The effluent quality of the reactor declined with the decrease in temperature.
View Article and Find Full Text PDFSci Rep
December 2024
Department of Earth and Planetary Sciences, University of California, Riverside, CA, 92521, USA.
The Salton Sea (SS), California's largest inland lake at 816 square kilometers, formed in 1905 from a levee breach in an area historically characterized by natural wet-dry cycles as Lake Cahuilla. Despite more than a century of untreated agricultural drainage inputs, there has not been a systematic assessment of nutrient loading, cycling, and associated ecological impacts at this iconic waterbody. The lake is now experiencing unprecedented degradation, particularly following the 2003 Quantification Settlement Agreement-the largest agricultural-to-urban water transfer in the United States.
View Article and Find Full Text PDFBioresour Technol
December 2024
Key Laboratory of Environmental Remediation and Ecological Health, Ministry of Industry and Information Technology, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing, Jiangsu, 210094, China; Engineering Research Centre of Chemical Pollution Control, Ministry of Education, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing, Jiangsu, 210094, China. Electronic address:
Anammox coupled partial S-driven autotrophic denitrification (PSAD) technology represents an innovative approach for removing nitrogen from wastewater. The research highlighted the crucial role of biofilm on sulfur particles in the nitrogen removal process. Further analysis revealed that sulfur-oxidizing bacteria (SOB) are primarily distributed in the inner layer of the biofilm, while anammox bacteria (AnAOB) are relatively evenly distributed in inner and outer layers, with Thiobacillus and Candidatus Brocadia being the dominant species, respectively.
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