Effect of Swelling by Organic Solvent on Structure, Pyrolysis, and Methanol Extraction Performance of Hefeng Bituminous Coal.

ACS Omega

Key Laboratory of Coal Clean Conversion & Chemical Engineering Process (Xinjiang Uyghur Autonomous Region), College of Chemical Engineering, Xinjiang University, Urumqi 830046, Xinjiang, China.

Published: June 2021

AI Article Synopsis

  • Different solvents (NMP, Py, THF, THN) were used to swell Hefeng acid-washed bituminous coal (HBC), with NMP showing the best swelling performance (a swelling degree of 2.11).
  • The FTIR analysis indicated that both the acid washing and swelling processes had minimal impact on the coal's macromolecule structure, meaning the coal remained intact.
  • Methanol extraction yields were higher after acid washing, achieving 3.21% for swelled HBC compared to 1.66% for unwashed HBC, suggesting that acid washing improved the extraction efficiency.

Article Abstract

-methyl-2-pyrrolidone (NMP), pyridine (Py), tetrahydrofuran (THF), and tetralin (THN) were used to swell Hefeng acid-washed bituminous coal (HBC). The swelling effect on HBC by each solvent is different, among which NMP presented well swelling performance, with a swelling degree of 2.11. FTIR results showed that acid washing and swelling processes presented a marginal effect on HBC, and there was no damage to the macromolecule structure of the coal. TG-DTG profiles of the swollen coals illustrated that the total weight loss of each sample was lower than that of the acid-washing one, while the temperature of the maximum weight loss rate peak was almost unchanged, around 445 °C. Extract yield by methanol followed the order of HBC > HBC > HBC (swelled by NMP), showing that acid washing promoted the methanol extraction process, with a higher extract yield of 3.21%, which is twice that of HBC (1.66%).

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8209798PMC
http://dx.doi.org/10.1021/acsomega.0c06105DOI Listing

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