The increasing concentration of CO in the atmosphere has led to the greenhouse effect, which greatly affects the climate and the ecological balance of nature. Therefore, converting CO into renewable fuels via clean and economical chemical processes has become a great concern for scientists. Electrocatalytic CO conversion is a prospective path toward carbon cycling. Among the different electrocatalysts, Sn-based electrocatalysts have been demonstrated as promising catalysts for CO electroreduction, producing formate and CO, which are important industrial chemicals. In this review, various Sn-based electrocatalysts are comprehensively summarized in terms of synthesis, catalytic performance, and reaction mechanisms for CO electroreduction. Finally, we concisely discuss the current challenges and opportunities of Sn-based electrocatalysts.
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http://dx.doi.org/10.1007/s40820-019-0293-x | DOI Listing |
J Colloid Interface Sci
January 2025
School of Liquor-making and Food Engineering, Guizhou University, Guiyang, Guizhou 550025, China.
Electrocatalytic CO reduction reaction (CORR) to formate offers a promising route for carbon neutralization, but its reactivity is largely compromised due to the competitive hydrogen evolution reaction (HER) accompanying the activation of CO at high potentials. Herein, we modulated the charge density around Sn atoms by introducing LaSnO into SnO, with the rich grain boundaries and fast electron transport of the heterostructure promoting CO reduction. Combined theoretical calculations and in situ electrochemical attenuated total reflection Fourier-transform infrared spectroscopy (ATR-FTIR) characterization revealed enhanced activation of CO and adsorption of *OCHO intermediates by the constructed electron-rich SnO.
View Article and Find Full Text PDFLangmuir
September 2024
State Key Laboratory of Electroanalytical Chemistry & Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, 130022 Changchun, P.R. China.
Chemistry
October 2024
School of Physics and Materials Science, Nanchang University, Nanchang, 330031, People's Republic of China.
Tin (Sn)-based materials are expected to realize efficient CO electroreduction into formate. Herein, we constructed a heterojunction by depositing Cu on Cu-doped SnS nanosheets. During the electrochemical reaction, this heterojunction evolves to a highly active phase of CuO@CuSn while maintaining its two-dimensional morphology.
View Article and Find Full Text PDFACS Appl Mater Interfaces
April 2024
Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80303, United States.
electrochemical attenuated total reflection surface-enhanced infrared absorption spectroscopy (EC ATR-SEIRAS) is a valuable method for a fundamental understanding of electrochemical interfaces under real operating conditions. The applicability of this method depends on the ability to tune the optical and catalytic properties of an electrode film, and it thus requires unique optimization for any given material. Motivated by the growing interest in Sn-based electrocatalysts for selective reduction of CO to formate species, we investigate several Sn thin-film synthesis routes for the resulting SEIRA signal response.
View Article and Find Full Text PDFNanomicro Lett
January 2024
School of Science, RMIT University, Melbourne, VIC, 3000, Australia.
Renewable energy driven N electroreduction with air as nitrogen source holds great promise for realizing scalable green ammonia production. However, relevant out-lab research is still in its infancy. Herein, a novel Sn-based MXene/MAX hybrid with abundant Sn vacancies, Sn@TiCT/TiSnC-V, was synthesized by controlled etching Sn@TiSnC MAX phase and demonstrated as an efficient electrocatalyst for electrocatalytic N reduction.
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