Photothermal membrane distillation (MD) is a promising technology for desalination and water purification. However, solar-thermal conversion suffers from low energy efficiency (a typical solar-water efficiency of ~ 50%), while complex modifications are needed to reduce membrane fouling. Here, we demonstrate a new concept of solar vapour gap membrane distillation (SVGMD) synergistically combining self-guided water transport, localized heating, and separation of membrane from feed solution. A free-standing, multifunctional light absorber based on graphene array is custom-designed to locally heat the thin water layer transporting through graphene nanochannels. The as-generated vapour passes through a gap and condenses, while salt/contaminants are rejected before reaching the membrane. The high solar-water efficiency (73.4% at 1 sun), clean water collection ratio (82.3%), excellent anti-fouling performance, and stable permeate flux in continuous operation over 72 h are simultaneously achieved. Meanwhile, SVGMD inherits the advantage of MD in microorganism removal and water collection, enabling the solar-water efficiency 3.5 times higher compared to state-of-the-art solar vapour systems. A scaled system to treat oil/seawater mixtures under natural sunlight is developed with a purified water yield of 92.8 kg m day. Our results can be applied for diverse mixed-phase feeds, leading to the next-generation solar-driven MD technology.
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http://dx.doi.org/10.1007/s40820-019-0281-1 | DOI Listing |
EES Solar
January 2025
Department of Chemical Engineering and Biotechnology, University of Cambridge Cambridge CB3 0AS UK.
Thermal co-evaporation of halide perovskites is a solution-free, conformal, scalable, and controllable deposition technique with great potential for commercial applications, particularly in multi-junction solar cells. Monolithic triple-junction perovskite solar cells have garnered significant attention because they can achieve very high efficiencies. Nevertheless, challenges arise in fabricating these devices, as they require multiple layers and precise current matching across complex absorber stacks.
View Article and Find Full Text PDFNanoscale
January 2025
College of Chemical Engineering, State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China.
Interfacial solar vapor generation (ISVG) accompanied by photocatalytic degradation holds immense potential to mitigate water scarcity and pollution. Distinct from the two detached functional components (photothermal agent and photocatalyst) in a conventional evaporator, in this study, an all-in-one photothermal/catalytic agent, nitrogen-containing honeycomb carbon nanosheets (NHC), was engineered for synergistic high-efficiency steam generation and photocatalysis functions. It was demonstrated that the superoxide radical generated on the surface of NHC conferred its catalytic activity to the photodegradation of organic pollutants under full solar spectrum irradiation.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Institute of Microstructure Technology (IMT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen 76344, Germany.
Established sequential deposition of multilayer two-terminal (2T) all-perovskite tandem solar cells possesses challenges for fabrication and limits the choice of materials and device architecture. In response, this work represents a lamination process based on a transparent and conductive adhesive that interconnects the wide-bandgap (WBG) perovskite top solar cell and the narrow-bandgap (NBG) perovskite bottom solar cell in a monolithic 2T all-perovskite tandem solar cell. The transparent conductive adhesive (TCA) layer combines Ag-coated poly(methyl methacrylate) microspheres with an optical adhesive.
View Article and Find Full Text PDFAdv Mater
January 2025
School of Energy and Power Engineering, Beihang University, Beijing, 100191, China.
Perovskite smart windows (PSWs) are widely investigated owing to excellent thermochromic properties, while restricted by poor transition performance and cycle stability. Herein, dimethyl sulfoxide vapor is utilized as an induction reagent for rapid reversible switching at room temperature between the colored and bleached phases. To obtain PSWs with different optical properties and transition performance, red CsPbIBr, yellow RbCsPbIBr and brown CsSnPbIBr are prepared through alloying.
View Article and Find Full Text PDFNanoscale
January 2025
College of Materials Science and Engineering, Hubei Provincial Engineering Research Center of Industrial Fiber Preparation and Application, Wuhan Textile University, Wuhan 430200, Hubei, China.
In recent years, solar-driven photothermal water evaporation technology for seawater desalination and wastewater treatment has developed rapidly, which is of great significance for addressing the issue of freshwater scarcity. However, due to the high costs associated with the manufacturing, maintenance, and operation of such devices, their application remains challenging in remote and resource-scarce regions. Due to its excellent light absorption capability in the near-infrared region, high hydrophilicity, and stable chemical properties, coupled with the low cost of recycling waste carbonized polyphenylene sulfide, this material is an excellent choice as a photothermal material for solar-driven water evaporation devices.
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