When choosing a treatment technology for nitrate or perchlorate removal, drinking water utilities overwhelmingly choose ion exchange. However, of late, biological treatment and point-of-use systems have received a great deal of attention. This article utilizes several new U.S. Environmental Protection Agency models to estimate the cost of nitrate and perchlorate treatment for small drinking water systems. The analysis here shows that, when comparing the three technologies for a typical set of design choices and drinking water quality conditions, the least-cost option varies among the three depending on system size. This relationship varies with changes to the water quality and design factors such as, but not restricted to, influent nitrate and perchlorate concentrations, the choice of residual management options, and the presence of co-contaminants and competing ions.
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http://dx.doi.org/10.1002/aws2.1224 | DOI Listing |
Toxics
December 2024
Department of Epidemiology and Biostatistics, School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, Wuhan 430030, China.
Classified as endocrine disrupting chemicals (EDCs), perchlorate, nitrate, and thiocyanate have been implicated with obesity and reproductive disorders. This study used three cycles of the National Health and Nutrition Examination Survey (NHANES 2013-2018); 813 women of reproductive age were finally included. We used multivariable logistic regression to analyze the associations between the three anions and obesity and infertility.
View Article and Find Full Text PDFChemosphere
January 2025
Department of Environmental Science, Baylor University, Waco, TX, USA. Electronic address:
Background: Perchlorate, nitrate, and thiocyanate are well-known sodium/iodide symporter (NIS) inhibitors that disturb iodide uptake at the thyroid, affecting thyroid function. However, the associations between NIS inhibitor exposure and thyroid function are not well summarized in humans.
Objective: We aimed to summarize associations between NIS inhibitor exposure and thyroid function markers and to identify key information gaps for future studies.
Ecotoxicol Environ Saf
January 2025
School of Public Health, Xinjiang Medical University, Urumqi, China. Electronic address:
Objectives: Perchlorates, nitrates, and thiocyanates constitute environmental endocrine disruptors; however, health damage caused by absorption through the respiratory tract remains poorly studied. We investigated the effects of inhalation of these pollutants on thyroid function and structure and serum metabolomics in pregnant rats.
Methods: We established a Sprague-Dawley pregnant rat model exposed to perchlorate, nitrate, and thiocyanate at different gestational stages and compared maternal serum thyroid function levels, foetal development, thyroid morphology, and pathological changes between exposed and non-exposed groups at different concentrations.
One very unique feature of oxidorhenium(v) complexes is their dual catalytic activity in both reduction of stable oxyanions like perchlorate ClO and nitrate NO as well as epoxidation of olefins. In our ongoing research efforts, we were interested to study how an electron-withdrawing ligand would affect both these catalytic reactions. Hence, we synthesized the novel bidentate dimethyloxazoline-dichlorophenol ligand HL1 and synthesized oxidorhenium(v) complex [ReOCl(L1)] (1).
View Article and Find Full Text PDFInorg Chem
January 2025
Department of Chemistry and Biochemistry, University of California, Santa Cruz, California 95064, United States.
Four new and one previously reported silver 4,4'-vinylenedipyridine (Vpe) coordination polymers were tested as anion exchange materials to assess their potential for pollutant sequestration and compared to analogous silver 4,4'-bipyridine (bipy) coordination polymers. The materials were synthesized using nitrate, tetrafluoroborate, perchlorate, perrhenate, or chromate as the anion to produce cationic coordination polymers with solubilities ranging from 0.0137(7) to 0.
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