A trigonal-bipyramidal covalent organic cage compound serves as an efficient host to form stable 1 : 1-complexes with C and C. Fullerene encapsulation has been comprehensively studied by NMR and UV/Vis spectroscopy, mass spectrometry as well as single-crystal X-ray diffraction. Exohedral functionalization of encapsulated C threefold Prato reaction revealed high selectivity for the symmetry-matched all--3 addition pattern.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163405 | PMC |
| http://dx.doi.org/10.1039/d0sc03131c | DOI Listing |
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