Particle-laden fluid/fluid interfaces are ubiquitous in academia and industry, which has fostered extensive research efforts trying to disentangle the physico-chemical bases underlying the trapping of particles to fluid/fluid interfaces as well as the properties of the obtained layers. The understanding of such aspects is essential for exploiting the ability of particles on the stabilization of fluid/fluid interface for the fabrication of novel interface-dominated devices, ranging from traditional Pickering emulsions to more advanced reconfigurable devices. This review tries to provide a general perspective of the physico-chemical aspects associated with the stabilization of interfaces by colloidal particles, mainly chemical isotropic spherical colloids. Furthermore, some aspects related to the exploitation of particle-laden fluid/fluid interfaces on the stabilization of emulsions and foams will be also highlighted. It is expected that this review can be used for researchers and technologist as an initial approach to the study of particle-laden fluid layers.
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http://dx.doi.org/10.1088/1361-648X/ac0938 | DOI Listing |
Langmuir
December 2024
Department of Mechanical Engineering and Materials Science, Duke University, Durham, North Carolina 27708, United States.
Fluid-fluid interfaces are an attractive platform for self-assembling nanoparticles into low-dimensional materials. In this Perspective, we review recent developments in the use of interfaces to direct the assembly of spherical and anisotropic nanoparticles into diverse and sophisticated architectures. We illustrate how nanoparticle clusters, strings, networks, superlattices, chiral lattices, and quasicrystals can be self-assembled by harnessing the frustration between interfacial and interparticle forces.
View Article and Find Full Text PDFPhys Rev E
October 2024
School of Mathematics and Statistics, The Open University, Walton Hall, Milton Keynes MK7 6AA, United Kingdom.
We present a two-phase field model and a hybrid particle-phase field model to simulate dilute colloidal sedimentation and flotation near a liquid-gas interface (or fluid-fluid interface in general). Both models are coupled to the incompressible Stokes equation, which is solved numerically using a combination of sine and regular Fourier transforms to account for the no-slip boundary conditions at the boundaries. The continuum two-phase field model allows us to analytically solve the equilibrium interfacial profile using a perturbative approach, demonstrating excellent agreement with numerical simulations.
View Article and Find Full Text PDFLangmuir
November 2024
ChampionX, 11177 S. Stadium Drive, Sugar Land, Texas 77478, United States.
Aqueous surfactant-nanoparticle mixtures have received great attention recently for promoting a more sustainable and efficient enhanced oil recovery (EOR) process. However, colloidal stability under reservoir conditions is considered a great challenge. In addition, the way synergy operates in EOR is not clearly understood.
View Article and Find Full Text PDFJ Chem Phys
September 2024
State Key Laboratory of Polymer Physics and Chemistry & Key Laboratory of Polymer Science and Technology, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 130022 Changchun, China.
The adsorption of polymer-grafted nanoparticles at interfaces is a problem of fundamental interest in physics and soft materials. This adsorption behavior is governed by the interplay between interaction potentials and entropic effects. Here, we use molecular dynamics simulations and umbrella sampling methods to study the adsorption behavior of a Janus-like homopolymer-grafted nanoparticle at fluid-fluid interfaces.
View Article and Find Full Text PDFJ Phys Condens Matter
September 2024
Institute of Applied Materials-Microstructure Modelling and Simulation, Karlsruhe Institute of Technology (KIT), Straße am Forum 7, 76131 Karlsruhe, Germany.
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