AI Article Synopsis
- Supramolecular chaperones help assemble protein subunits and metal ions into complex structures, specifically 2D and 3D nanocapsules when combined with hydroxyl-tailed ligands and Mn ions.
- The dimensionality of these nanocapsules is influenced by how their subunits interact and the use of proline chaperones facilitates the encapsulation of certain functions within the 2D structures.
- These nanocapsules demonstrate optimized surface properties for enhanced functionality, proving to be effective electrocatalysts for water oxidation with a low overpotential at near-neutral pH.
Article Abstract
Supramolecular chaperones play an important role in directing the assembly of multiple protein subunits and redox-active metal ions into precise, complex and functional quaternary structures. Here we report that hydroxyl tailed -alkylpyrogallol[4]arene ligands and redox-active Mn ions, with the assistance of proline chaperone molecules, can assemble into two-dimensional (2D) and/or three-dimensional (3D) networked nanocapsules. Dimensionality is controlled by coordination between the exterior of nanocapsule subunits, and endohedral functionalization within the 2D system is achieved chaperone guest encapsulation. The tailoring of surface properties of nanocapsules coordination chemistry is also shown as an effective method for the fine-tuning magnetic properties, and electrochemical and spectroscopic studies support that the nanocapsule is an effective homogeneous water-oxidation electrocatalyst, operating at pH 6.07 with an exceptionally low overpotential of 368 mV.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163202 | PMC |
| http://dx.doi.org/10.1039/d0sc05002d | DOI Listing |
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