We here report on a facile method for preparation of gold nanostar-graphene quantum dot (AuNS@GQD) composite, which produces highly active surfactant-free AuNSs. The etching reaction of this composite with NaSO was studied and used as a new sensing strategy for colorimetric detection of nM levels of cysteine. In the presence of NaSO, the shape of AuNSs changes to sphere-like nanoparticles, leading to a distinct color change of solution from light green to indigo. This phenomenon results from the redox reaction of Au atoms at the apexes and sharp corners of the NSs with oxygen which leads to the formation of [Au(SO)]. Our studies indicated that the stars with larger sizes show greater activity in etching reaction since they have more branches and sharper tips. Due to the strong coordination between Au and thiols, pre-added cysteine can protect the AuNSs from SO etching and so the shape and the color of AuNSs remain unaltered. This anti-etching effect was used for the detection of cysteine with the detection limit as low as 0.35 nM. The developed colorimetric sensor was validated by HPLC method and applied for analysis of human plasma samples.
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