This work presents the elimination of arsenic ions from synthetic produced water via hollow fiber supported liquid membrane (HFSLM). Results demonstrate that arsenic ions in synthetic wastewater can be successfully treated to meet the wastewater standard as formulated by the Ministry of Industry and the Ministry of Natural Resources and Environment, Thailand. The discharged limit of arsenic from industrial wastewater must not be greater than 250 ppb. In a single-step operation, arsenic ions are extracted and stripped. Percentages of extraction and stripping proved to be 100% and 98%, respectively. Optimum conditions found proved to be 0.68 M Aliquat 336 dissolved in toluene as the liquid membrane, at pH 12 of feed solution, having a mixture of HCl and thiourea as the synergistic strippant, and flow rates of both feed and strippant solutions of 100 mL/min. A mathematical model, developed to predict the final concentration of arsenic ions in feed and strippant solutions, is seen to fit in well with the experimental results.
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http://dx.doi.org/10.1038/s41598-021-91326-9 | DOI Listing |
J Environ Sci (China)
July 2025
State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; University of Chinese Academy of Sciences, Beijing 100049, China. Electronic address:
Arsenic (As) and antimony (Sb), with analogy structure, belong to VA group in the periodic table and pose a great public concern due to their potential carcinogenicity. The speciation distribution, migration and transformation, enrichment and retention, as well as bioavailability and toxicity of As and Sb are influenced by several environmental processes on mineral surfaces, including adsorption/desorption, coordination/precipitation, and oxidation/reduction. These interfacial reactions are influenced by the crystal facet of minerals with different atomic and electronic structures.
View Article and Find Full Text PDFJ Environ Sci (China)
July 2025
Key Laboratory of Pollution Ecology and Environmental Engineering, Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang 110016, China. Electronic address:
In sulfidic anoxic environments, iron sulfides are widespread solid phases that play an important role in the arsenic (As) biogeochemical cycle. This work investigated the transformation process of FeS-As coprecipitates, the concurrent behavior, and the speciation of associated As under anoxic conditions. The results showed that FeS-As coprecipitates could convert to greigite and pyrite.
View Article and Find Full Text PDFJ Environ Sci (China)
July 2025
John A. Reif, Jr. Department of Civil and Environmental Engineering, New Jersey Institute of Technology, Newark, New Jersey 07102, USA.
In this study, synthetic wastewater containing 110 µg/L arsenate (As(V)), 0-20 mg/L fulvic acid (FA), and 0-12.3 mg/L phosphate was treated with 3 mg/L Fe. The mechanisms of FA and phosphate effects on As(V) removal by ferric chloride were determined using 0.
View Article and Find Full Text PDFJ Environ Sci (China)
July 2025
Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control, School of Environmental Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, China; State Environmental Protection Key Laboratory of Integrated Surface Water-Groundwater Pollution Control, School of Environmental Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, China; Shenzhen Key Laboratory of Precision Measurement and Early Warning Technology for Urban Environmental Health Risks, School of Environmental Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, China. Electronic address:
Rapid screening of inorganic arsenic (iAs) in groundwater used for drinking by hundreds of millions of mostly rural residents worldwide is crucial for health protection. Most commercial field test kits are based on the Gutzeit reaction that uses mercury-based reagents for color development, an environmental concern that increasingly limits its utilization. This study further improves the Molybdenum Blue (MB) colorimetric method to allow for faster screening with more stable reagents.
View Article and Find Full Text PDFJ Environ Sci (China)
July 2025
Key Laboratory of Pollution Ecology and Environmental Engineering, Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang 110016, China.
Siderite tailings is a potentially cost-free iron (Fe) source for arsenic (As) fixation in hazardous arsenic-calcium residues (ACR) as stable scorodite. In this study, a pure siderite reagent was employed to investigate the mechanism and optimal conditions for As fixation in ACR via scorodite formation, while the waste siderite tailings were used to further demonstrate the cotreatment method. The cotreatment method starts with an introduction of sulfuric acid to the ACR for As extraction and gypsum precipitation, and is followed by the addition of HO to oxidize As(III) in the extraction solutions and finalized by adding siderite with continuous air injection for scorodite formation.
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