Electrocaloric materials are promising working bodies for caloric-based technologies, suggested as an efficient alternative to the vapor compression systems. However, their materials efficiency defined as the ratio of the exchangeable electrocaloric heat to the work needed to trigger this heat remains unknown. Here, we show by direct measurements of heat and electrical work that a highly ordered bulk lead scandium tantalate can exchange more than a hundred times more electrocaloric heat than the work needed to trigger it. Besides, our material exhibits a maximum adiabatic temperature change of 3.7 K at an electric field of 40 kV cm. These features are strong assets in favor of electrocaloric materials for future cooling devices.
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http://dx.doi.org/10.1038/s41467-021-23354-y | DOI Listing |
Nat Commun
January 2025
Department of Polymer Science and Engineering, Key Laboratory of High-Performance Polymer Materials and Technology of MOE, State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry & Chemical Engineering, Nanjing University, Nanjing, China.
Overheating remains a major barrier to chip miniaturization, leading to device malfunction. Addressing the urgent need for thermal management promotes the development of solid-state electrocaloric cooling. However, enhancing passive heat dissipation through two-dimensional materials in electrocaloric polymers typically compromises the electrocaloric effect.
View Article and Find Full Text PDFSoft Matter
January 2025
Advanced Materials and Liquid Crystal Institute, Kent State University, Kent, OH, 44242, USA.
Electrocaloric effects (ECE) in solid state materials, such as ferroelectric ceramics and ferroelectric polymers, have a great impact in developing cooling systems. Herein, we describe the ECE of a newly synthesized ferroelectric nematic liquid crystal compound at the isotropic-ferroelectric nematic (I-N) phase transition. While the Joule heat completely suppressed the ECE in a DC field, in an AC field with < 1.
View Article and Find Full Text PDFJ Am Chem Soc
November 2024
Advanced Materials Department, Jožef Stefan Institute, Jamova Cesta 39, Ljubljana 1000, Slovenia.
Sm-doped Pb(MgNb)O-PbTiO (Sm-PMN-PT) bulk materials have revealed outstanding ferroelectric and piezoelectric properties due to enhanced local structural heterogeneity. In this study, we further explore the potential of Sm-PMN-PT by fabricating epitaxial thin films by pulsed laser deposition, revealing that Sm doping significantly improves the capacitive energy-storage, piezoelectric, electrocaloric, and pyroelectric properties of PMN-PT thin films. These Sm-PMN-PT thin films exhibit fatigue-free performance up to 10 charge-discharge cycles and maintain thermal stability across a wide temperature range from -40 to 200 °C.
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2024
CAS Key Laboratory of Materials for Energy Conversion and Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, 230026, China.
Poly(vinylidenefluoride-trifluoroethylene-chlorotrifluoroethylene) (P(VDF-TrFE-CTFE)) relaxor ferroelectric polymer exhibits a modest electrocaloric effect (ECE) at a low electric field near room temperature and a low thermal conductivity. The low thermal conductivity causes poor heat transfer when the terpolymer is used as a cooling device, even when the ECE of the polymer is substantial. By incorporating aluminum nitride (AlN) nanoparticles, which possess high thermal conductivity and good electrical insulation properties, into polymer matrices, we can enhance both the thermal conductivity and the ECE.
View Article and Find Full Text PDFMaterials (Basel)
October 2024
Guangdong Provincial Research Center on Smart Materials and Energy Conversion Devices, Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China.
In order to obtain large room-temperature electrocaloric effect (ECE) and wide operation temperature range simultaneously in lead-free ceramics, we proposed designing a relaxor ferroelectric with a (the temperature at which the maximum dielectric permittivity is achieved) near-room temperature and glass addition. Based on this strategy, we designed and fabricated lead-free 0.76NaNbO-0.
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