AI Article Synopsis
- - A new chromatographic stationary phase made of silica-bound -butylpyrogallol[4]arene was created and analyzed using techniques like thermogravimetric analysis and scanning electron microscopy.
- - The effectiveness of this new phase was tested with C60 and C70 fullerenes in reverse phase chromatography, showing it outperformed traditional methods in separating these molecules.
- - The study also found that including toluene in the mobile phase helps improve the symmetry of peaks during flash column chromatography.
Article Abstract
A silica-bound -butylpyrogallol[4]arene chromatographic stationary phase was prepared and characterised by thermogravimetric analysis, scanning electron microscopy, NMR and mass spectrometry. The chromatographic performance was investigated by using C and C fullerenes in reverse phase mode via flash column and high-pressure liquid chromatography (HPLC). The resulting new stationary phase was observed to demonstrate size-selective molecular recognition as postulated from our in-silico studies. The silica-bound -butylpyrogallol[4]arene flash and HPLC stationary phases were able to separate a C- and C-fullerene mixture more effectively than an RP-C stationary phase. The presence of toluene in the mobile phase plays a significant role in achieving symmetrical peaks in flash column chromatography.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8198677 | PMC |
| http://dx.doi.org/10.3390/ijms22115726 | DOI Listing |
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