Herein, the effect of three deterpenated fractions from L. essential oil on the physicochemical, mechanical and biological properties of chitosan/β-chitin nanofibers-based nanocomposite films were investigated. In general, the incorporation of L. original essential oil or its deterpenated fractions increases the opacity of the nanocomposite films and gives them a yellowish color. The water solubility decreases from 58% for chitosan/β-chitin nanofibers nanocomposite film to around 32% for the nanocomposite films modified with original essential oil or its deterpenated fractions. Regarding the thermal stability, no major changes were observed, and the mechanical properties decreased. Interestingly, data show differences on the biological properties of the materials depending on the incorporated deterpenated fraction of L. essential oil. The nanocomposite films prepared with the deterpenated fractions with a high concentration of oxygenated terpene derivatives show the best antifungal activity against , with fungal growth inhibition of around 85.90%. Nonetheless, the only nanocomposite film that does not present cytotoxicity on the viability of L929 fibroblast cells after 48 and 72 h is the one prepared with the fraction presenting the higher terpenic hydrocarbon content (87.92%). These results suggest that the composition of the deterpenated fraction plays an important role in determining the biological properties of the nanocomposite films.
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http://dx.doi.org/10.3390/polym13091507 | DOI Listing |
Polymers (Basel)
January 2025
Department of Biochemistry, Institute for Biological Research "Siniša Stanković"-National Institute of the Republic of Serbia, University of Belgrade, Bulevar despota Stefana 142, 11060 Belgrade, Serbia.
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View Article and Find Full Text PDFMaterials (Basel)
January 2025
Department of Fisheries, Faculty of Fisheries and the Environment, Gorgan University of Agricultural Sciences and Natural Resources, Gorgan 4913815739, Iran.
One of the main limitations of biopolymers compared to petroleum-based polymers is their weak mechanical and physical properties. Recent improvements focused on surmounting these constraints by integrating nanoparticles into biopolymer films to improve their efficacy. This study aimed to improve the properties of gelatin-chitosan-based biopolymer layers using zinc oxide (ZnO) and graphene oxide (GO) nanoparticles combined with spermidine to enhance their mechanical, physical, and thermal properties.
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January 2025
Department of Applied Chemistry, Faculty of Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555, Japan.
Self-healable, multilayered organosiloxane films were prepared thermal conversion of lamellar organosiloxane films containing poly(ethylene oxide)-polydimethylsiloxane-poly(ethylene oxide) block copolymers. The incorporation of silanolate groups enabled crack healing through dynamic siloxane equilibration. The enhanced hardness and suppressed cyclic siloxane formation resulting from the multilayered structure exhibit potential for practical applications.
View Article and Find Full Text PDFFood Res Int
February 2025
Ghent University, Department of Applied Physics, Research Unit Plasma Technology (RUPT), Belgium.
Recently, interest in eco-friendly techniques for producing antibacterial food packaging films has surged. Within this context, plasma polymerization is emerging as a promising approach for applying degradable antibacterial coatings on various plastic films. This research therefore employs an atmospheric pressure aerosol-assisted plasma deposition technique to create polyethylene glycol (PEG)-like coatings embedding zinc oxide nanoparticles (ZnO NPs) of varying sizes on polyethylene (PE) substrates.
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March 2025
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China; Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry (CAF), No 16, Suojin Wucun, Nanjing, China. Electronic address:
Achieving effective interfacial compatibility between hydrophilic cellulose nanofibrils (CNFs) and hydrophobic vegetable oil polymers (VOPs) remained a significant challenge. To address this issue, we developed a one-component nanocomposite (OCN) based on hyperbranched CNF-grafted VOPs. Rigid precursor initiator poly (vinylbenzyl chloride) (PVBC) was first grafted onto the CNF surface via phase-transfer catalysis, forming a branched macroinitiator (CNF-g-PVBC) with chlorine contents ranging from 4.
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