An iron-sulfur complex formed by the simple mixture of FeCl with S generated in situ from KS is developed and applied to selective aerobic oxidation of terminal alkenes. The reaction was carried out under an atmosphere of O (balloon) and could proceed on a gram scale, expanding the application of S in organic synthesis. This study also encourages us to explore the application of an Fe-S catalyst in organic reactions.
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| http://dx.doi.org/10.1021/acs.orglett.1c01408 | DOI Listing |
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