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Determination of the π-Accepting Properties of Borate-, Aluminate-, and Gallate-Functionalized N-Heterocyclic Carbenes by Se NMR Spectroscopy. | LitMetric
Anionic N-heterocyclic carbenes with weakly coordinating borate, aluminate, and gallate moieties of the type [(FC)E-NHC] (E = B, Al, Ga) were isolated as lithium salts by the lithiation of 1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene (IMes) or 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene (IDipp) followed by the addition of E(CF) (E = B, Al, Ga). Treatment with elemental selenium afforded the lithium salts of the corresponding anionic selenourea derivatives [{(FC)E-NHC}Se] (NHC = IMes, E = B; NHC = IDipp, E = B, Al, Ga), which were examined, among other things, by means of Se{H} NMR spectroscopy to assess the π-accepting properties of the WCA-NHC ligands in comparison with their neutral NHC congeners.
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