1-Aza-2,4-disilabicyclo[1.1.0]butanes with Superelongated C-N σ-Bonds.

Two silylene molecules oxidatively react under formal [1 + 2 + 1]-cycloaddition to the C≡N bond of nitriles to yield 1-aza-2,4-disilabicyclo[1.1.0]butanes (L)(Cl)Si[μ-η-NC(-RCH)]Si(Cl)(L) (L = PhC(NBu), R = CF (), F (), Cl (), Br ()). The strongly folded bicyclic SiCNSi cores in - feature inverted bridgehead carbon atoms and superelongated C-N bonds [1.745(12) to 1.801(2) Å], exceeding the lengths of C-N single bonds in known silaaziridines by up to 23%. Detailed bonding analysis discloses C-N bonding interactions, sharing far-reaching similarities with the central C-C bond in [1.1.1]propellane.