Synthetic approaches for accessing rare-earth analogues of UiO-66.

Chem Commun (Camb)

Department of Chemistry and Biochemistry, and Centre for NanoScience Research, Concordia University, 7141 Sherbrooke St W., Montréal, QC H4B 1R6, Canada.

Published: June 2021

Rare-earth (RE) analogues of UiO-66 with non-functionalised 1,4-benzenedicarboxylate linkers are synthesised for the first time, and a series of synthetic approaches is provided to troubleshoot the synthesis. RE-UiO-66 analogues are fully characterised, and demonstrate a high degree of crystallinity, high surface area and thermal stability, consistent with the UiO-66 archetype.

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Source
http://dx.doi.org/10.1039/d1cc01552dDOI Listing

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