Research in the development of molecular organic photocatalysts for applications in chemical syntheses has burgeoned in recent years. While organic photosensitizers have been known for over a century, tuning the properties of these molecules to increase photocatalytic efficiencies is now of growing importance. The properties that help improve the performance of organic photocatalysts include: a wider range of redox potentials, increased molar absorptivity (ε) in the visible spectrum, increased quantum yields (Φ), long-lived excited-state lifetimes (ns to μs), and increased chemical stability. This review examines some of the recent advancements in the development of molecular organic photocatalysts, specifically cyanoarenes, acridinium dyes, phenazines, thiazines, oxazines, and xanthenes, with respect to these properties and examines the chemical synthesis routes now achieved by organic photocatalysts.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d1ob00396h | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Putting Charge Transfer Degree as a Bridge Connecting Surface-Enhanced Raman Spectroscopy and Photocatalysis.
Angew Chem Int Ed Engl
January 2025
Jilin University, State Key Laboratory of Supramolecular Structure and Materials, 2699 Qianjin Street, 130012, Changchun, CHINA.
To date, few systematic approach has been established for predicting catalytic performance by analyzing the spectral information of molecules adsorbed on photocatalyst surfaces. Effective charge transfer (CT) between the semiconductor photocatalysts and surface-absorbed molecules is essential for enhancing catalytic activity and optimizing light energy utilization. This study aimed to validate the surface-enhanced Raman spectroscopy (SERS) based on the CT enhancement mechanism in investigating the CT process during semiconductor photocatalytic C-C coupling model reactions.
View Article and Find Full Text PDFNoble-Metal-Free ZnII-Anchored Pyrene-Based Covalent Organic Framework (COF) for Photocatalytic Fixation of CO2 from Dilute Gas into Bioactive 2-Oxazolidinones.
ChemSusChem
January 2025
Indian Institute of Technology Ropar, Chemistry, Nangal Road, 140001, Rupnagar, INDIA.
Photocatalytic conversion of CO2 into value-added chemicals offers a propitious alternative to traditional thermal methods, contributing to environmental remediation and energy sustainability. In this respect, covalent organic frameworks (COFs), are crystalline porous materials showcasing remarkable efficacy in CO2 fixation facilitated by visible light owing to their excellent photochemical properties. Herein, we employed Lewis acidic Zn(II) anchored pyrene-based COF (Zn(II)@Pybp-COF) to facilitate the photocatalytic CO2 utilization and transformation to 2-oxazolidinones.
View Article and Find Full Text PDFPhotodegradation of aqueous tetracycline using CuS@TiO₂ composite under solar-simulated light: Complete mineralization, catalyst efficiency, and reusability.
Heliyon
January 2025
Department of Chemistry, An-Najah National University, Nablus, Palestine.
While CuS/TiO₂ has been previously synthesized and employed in a limited number of photodegradation studies, the current study investigated its effectiveness for TC degradation under UV-visible light irradiation. CuS is known to be a nontoxic, environmentally friendly material; hence, it has great potential as an alternative to CdS and CdSe, which are used conventionally as sensitizers. In this work, the CuS/TiO₂ photocatalysts achieved a maximum 95 % removal of TC at an initial concentration of 20 ppm, confirming the good utilization of active sites.
View Article and Find Full Text PDFTandem construction of flavone-bridged conjugated porous polymers for photosynthesis of 2,3-dihydrobenzofurans.
Chem Commun (Camb)
January 2025
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, 222 South Tianshui Road, Lanzhou 730000, P. R. China.
Conjugated porous polymers bearing flavone moieties (FL-CPPs) were synthesized a tandem approach. The carbonylative Sonogashira coupling in tandem with cyclization guided the assembling of building blocks with the accompanied production of flavone skeletons. The FL-CPPs were proved to be efficient metal-free photocatalysts for the [3+2] cycloaddition of phenols with olefins under the irradiation of visible-light.
View Article and Find Full Text PDFEnhanced photocatalytic degradation of Rhodamine B using polyaniline-coated XTiO(X = Co, Ni) nanocomposites.
Sci Rep
January 2025
Laboratory of Materials, Nanotechnologies and Environment, Center of Sciences of Materials, Faculty of Sciences, Mohammed V University in Rabat, Avenue Ibn Battouta, BP:1014, 10000, Rabat, Morocco.
In this study, novel polyaniline-coated perovskite nanocomposites (PANI@CoTiO and PANI@NiTiO) were synthesized using an in situ oxidative polymerization method and evaluated for the photocatalytic degradation of Rhodamine B (RhB) a persistent organic pollutant. The nanocomposites displayed significantly enhanced photocatalytic efficiency compared to pure perovskites. The 1%wt PANI@NiTiO achieved an impressive 94% degradation of RhB under visible light after 180 min, while 1wt.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!