Recent theoretical studies have predicted that adiabatic compressed air energy storage (ACAES) can be an effective energy storage option in the future. However, major experimental projects and commercial ventures have so far failed to yield any viable prototypes. Here we explore the underlying reasons behind this failure. By developing an analytical idealized model of a typical ACAES design, we derive a design-dependent efficiency limit for a system with hypothetical, perfect components. This previously overlooked limit, equal to 93.6% under continuous cycling for a typical design, arises from irreversibility associated with the transient pressure in the system. Although the exact value is design dependent, the methodology we present for finding the limit is applicable for a wide range of designs. Turning to real systems, the limit alone does not fully explain the failure of practical ACAES research. However, reviewing the available evidence alongside our analytical model, we reason that underestimation of the system complexity, difficulty with the integration of off-the-shelf components, and a number of misleading performance claims are the primary reasons hindering ACAES development.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8111675PMC
http://dx.doi.org/10.1016/j.isci.2021.102440DOI Listing

Publication Analysis

Top Keywords

energy storage
16
adiabatic compressed
8
compressed air
8
air energy
8
energy
4
storage
4
storage viable
4
viable energy
4
storage option?
4
option? theoretical
4

Similar Publications

High-performance supercapacitors based on coarse nanofiber bundle and ordered network hydrogels.

Int J Biol Macromol

December 2024

Jiangsu Key Laboratory of Sericultural and Animal Biotechnology, School of Biotechnology, Jiangsu University of Science and Technology, Zhenjiang 212100, China; Key Laboratory of Silkworm and Mulberry Genetic Improvement, Ministry of Agriculture and Rural Affairs, Sericultural Scientific Research Center, Chinese Academy of Agricultural Sciences, Zhenjiang 212100, China.

Most of the developed flexible hydrogel supercapacitors struggle to maintain their electrochemical stability and structural integrity under tensile strain. Therefore, developing a flexible supercapacitor with excellent mechanical properties and stable electrochemical performance under different strains remains a challenge. Based on the previous cartilage-like structure, we designed a new coarse nanofiber bundle and ordered network.

View Article and Find Full Text PDF

Machine Learning Boosted Entropy-Engineered Synthesis of CuCo Nanometric Solid Solution Alloys for Near-100% Nitrate-to-Ammonia Selectivity.

ACS Appl Mater Interfaces

December 2024

Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, 214122 Jiangsu, China.

Nanometric solid solution alloys are utilized in a broad range of fields, including catalysis, energy storage, medical application, and sensor technology. Unfortunately, the synthesis of these alloys becomes increasingly challenging as the disparity between the metal elements grows, due to differences in atomic sizes, melting points, and chemical affinities. This study utilized a data-driven approach incorporating sample balancing enhancement techniques and multilayer perceptron (MLP) algorithms to improve the model's ability to handle imbalanced data, significantly boosting the efficiency of experimental parameter optimization.

View Article and Find Full Text PDF

This study presents the preparation and electrochemical testing of sulfonated styrene-grafted poly(vinylidene fluoride) (pVDF) copolymers as proton exchange membranes (PEMs) for semi-organic redox flow batteries (RFBs) based on 9,10-anthraquinone-2,7-disulfonic acid (AQDS)/bromine. The copolymers are synthesized via a two-step procedure, involving i) atom transfer radical polymerization of styrene (Sty) for the grafting to the pVDF backbone and ii) the sulfonation of the polystyrene grafted side chains. Copolymers with different amounts of sulfonated styrene (SSty) in the side chains (i.

View Article and Find Full Text PDF

The design of cathode/electrolyte interfaces in high-energy density Li-ion batteries is critical to protect the surface against undesirable oxygen release from the cathodes when batteries are charged to high voltage. However, the involvement of the engineered interface in the cationic and anionic redox reactions associated with (de-)lithiation is often ignored, mostly due to the difficulty to separate these processes from chemical/catalytic reactions at the cathode/electrolyte interface. Here, a new electron energy band diagrams concept is developed that includes the examination of the electrochemical- and ionization- potentials evolution upon batteries cycling.

View Article and Find Full Text PDF

Nonporous TiO@C microsphere with a highly integrated structure for high volumetric lithium storage and enhance initial coulombic efficiency.

Sci Rep

December 2024

Shandong Engineering Research Center of Green and High-value Marine Fine Chemical, Weifang University of Science and Technology, Shouguang, 262700, People's Republic of China.

To enhance the volumetric energy density and initial coulombic efficiency (ICE) of titanium oxide (TiO) as anode electrode material for lithium-ion batteries (LIB), this study employed a surface-confined in-situ inter-growth mechanism to prepare a TiO embedded carbon microsphere composite. The results revealed that the composite exhibited a highly integrated structure of TiO with oxygen vacancies and carbon, along with an exceptionally small specific surface area of 11.52 m/g.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!