CO Chemisorption Behavior of Coordination-Derived Phenolate Sorbents.

CO chemisorption via C-O bond formation is an efficient methodology in carbon capture especially using phenolate-based ionic liquids (ILs) as the sorbents to afford carbonate products. However, most of the current IL systems involve alkylphosphonium cations, leading to side reactions via the ylide intermediate pathway. It is important to figure out the CO chemisorption behavior of phenolate-derived sorbents using inactive and easily accessible cation counterparts without active protons. Herein, phenolate-based systems were constructed via coordination between alkali metal cations with crown ethers to avoid the participation of active protons in CO chemisorption. Reaction pathway study revealed that CO uptake could be achieved by O-C bond formation to afford carbonate. CO uptake capacity and reaction enthalpy were significantly influenced by the coordination effect, alkali metal types, and alkyl groups on the benzene ring.