We use femtosecond laser-based two-photon polymerization (TPP) to fabricate a 2.5D micropillar array. Using an angular detection setup, we characterize the structure's scattering properties and compare the results against simulation results obtained from a novel electrodynamics simulation method. The algorithm employs a modified formulation of the Lorentz Oscillator Model and a leapfrog time differentiation to define a 2D coupled Oscillator Finite-Difference Time-Domain (O-FDTD). We validate the model by presenting several simulation examples that cover a wide range of photonic components, such as multi-mode interference splitters, photonic crystals, ring resonators, and Mach-Zehnder interferometers.
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http://dx.doi.org/10.1364/OE.414211 | DOI Listing |
J Chem Theory Comput
January 2025
Center for Computational Quantum Physics, The Flatiron Institute, 162 Fifth Avenue, New York, New York, 10010, United States.
We present a generalization of the phaseless auxiliary-field quantum Monte Carlo (AFQMC) method to cavity quantum-electrodynamical (QED) matter systems. The method can be formulated in both the Coulomb and the dipole gauge. We verify its accuracy by benchmarking calculations on a set of small molecules against full configuration interaction and state-of-the-art QED coupled cluster (QED-CCSD) calculations.
View Article and Find Full Text PDFChem Asian J
January 2025
Departamento de Química, Facultad de Ciencias, Universidad de Chile, Las Palmeras 3425, 7800003, Santiago, Chile.
Plasmonic materials can be utilized as effective platforms to enhance luminescent signals of luminescent metal nanoclusters (LMNCs). Both surface enhanced fluorescence (SEF) and shell-isolated nanoparticle-enhanced fluorescence (SHINEF) strategies take advantage of the localized and increased external electric field created around the plasmonic metal surface when excited at or near their characteristic plasmonic resonance. In this context, we present an experimental and computational study of different plasmonic composites, (Ag) Ag@SiO and (Au) Au@SiO nanoparticles, which were used to enhance the luminescent signal of Au nanoclusters coated with glutathione (GSH) molecule (AuGSH NCs).
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January 2025
Department of Theoretical Electrical Engineering and Diagnostics of Electrical Equipment, Institute of Electrodynamics, National Academy of Sciences of Ukraine, Beresteyskiy, 56, Kyiv-57, Kyiv, 03680, Ukraine.
This paper proposes an advanced Load Frequency Control (LFC) strategy for two-area hydro-wind power systems, using a hybrid Long Short-Term Memory (LSTM) neural network combined with a Genetic Algorithm-optimized PID (GA-PID) controller. Traditional PID controllers, while extensively used, often face limitations in handling the nonlinearities and uncertainties inherent in interconnected power systems, leading to slower settling time and higher overshoot during load disturbances. The LSTM + GA-PID controller mitigates these issues by utilizing LSTM's capacity to learn from historical data by using gradient descent to forecast the future disturbances, while the GA optimizes the PID parameters in real time, ensuring dynamic adaptability and improved control precision.
View Article and Find Full Text PDFInt J Mol Sci
December 2024
Department of Biotechnology, Chemistry and Pharmacy, University of Siena, 53100 Siena, Italy.
Living systems cannot rely on random intermolecular approaches toward cell crowding, and hidden mechanisms must be present to favor only those molecular interactions required explicitly by the biological function. Electromagnetic messaging among proteins is proposed from the observation that charged amino acids located on the protein surface are mostly in adjacent sequence positions and/or in spatial proximity. Molecular dynamics (MD) simulations have been used to predict electric charge proximities arising from concerted motions of charged amino acid side chains in two protein model systems, human ubiquitin and the chitinolytic enzyme from .
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December 2024
Department of Theoretical Electrical Engineering and Diagnostics of Electrical Equipment, Institute of Electrodynamics, National Academy of Sciences of Ukraine, Beresteyskiy, 56, Kyiv-57, Kyiv, 03680, Ukraine.
The rapid global adoption of electric vehicles (EVs) necessitates the development of advanced EV charging infrastructure to meet rising energy demands. In particular, community parking lots (CPLs) offer significant opportunities for coordinating EVs' charging. By integrating energy storage systems (ESSs), renewable energy sources (RESs), and building prosumers, substantial reductions in peak load and electricity costs can be achieved, while simultaneously promoting environmental sustainability.
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