Alcohol ethoxysulfates (AES) in environmental matrices.

Environ Sci Pollut Res Int

School of Environmental Studies, Cochin University of Science and Technology, Kochi, Kerala, 682022, India.

Published: July 2021

AI Article Synopsis

  • Extensive use of surfactants, like alcohol ethoxysulfates (AES) and linear alkyl benzene sulfonates (LAS), leads to their accumulation in soil, sediment, and water, raising concerns for both aquatic and human health.
  • The review focuses on AES, highlighting its toxicity, ecological impact, and the need for more research compared to LAS, which has received more attention in existing literature.
  • It also covers advancements in detecting AES in the environment and discusses potential strategies for its removal from various environmental compartments globally.

Article Abstract

Extensive use of surfactants in numerous fields resulted in their discharge into various environmental compartments including soil, sediment, and water. Alcohol ethoxysulfates (AES) together with alcohol ethoxylates (AE), alkyl sulfates (AS), and linear alkyl benzene sulfonates (LAS) find wide variety of applications in consumer products including both domestic and industrial applications. Consequently, all these surfactants pose several concerns to both aquatic and human health. In the context of environmental impacts, AES has almost equal importance as that of LAS though the literature on this topic is only emerging. This review provides a detailed overview on the various aspects of the anionic surfactant, AES, such as toxicity of AES, its fate in the ecosystem, technical advancements in the area of identification and quantification, its occurrence and distribution in different environmental compartments spanning across the world, and finally a remark of its potential removal strategy from the environment.

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http://dx.doi.org/10.1007/s11356-021-14003-4DOI Listing

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Article Synopsis
  • Extensive use of surfactants, like alcohol ethoxysulfates (AES) and linear alkyl benzene sulfonates (LAS), leads to their accumulation in soil, sediment, and water, raising concerns for both aquatic and human health.
  • The review focuses on AES, highlighting its toxicity, ecological impact, and the need for more research compared to LAS, which has received more attention in existing literature.
  • It also covers advancements in detecting AES in the environment and discusses potential strategies for its removal from various environmental compartments globally.
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Article Synopsis
  • The study focuses on monitoring major surfactants in water, particularly emphasizing alcohol ethoxysulfates (AES) in India using LC-Q-ToF-MS for their identification and quantification.
  • Results showed varying concentrations of AES and indicated that higher chain AES pose medium risk to aquatic environments, while also revealing that the water is acidic with high salinity and total dissolved solids (TDS).
  • Lastly, the water quality index (WQI) assessment categorized the water quality as "very poor," highlighting the potential impact of local canals on the receiving Vembanad Lake.
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Sorption, degradation and transport phenomena of alcohol ethoxysulfates in agricultural soils. Laboratory studies.

Chemosphere

March 2017

Research Group of Analytical Chemistry and Life Sciences, Department of Analytical Chemistry, Faculty of Sciences, University of Granada, Granada, Spain.

In the present work, laboratory studies were conducted in order to determine and model the sorption, degradation and transport processes of alcohol ethoxysulfates (AES), one of the most important groups of anionic surfactants. Adsorption/desorption isotherms were obtained for several structurally related AES ethoxymers (homologue AES-CE with n = 0-10 ethoxymer units and homologue AES-CE with n = 0-7 ethoxymer units) using a batch equilibrium method. Data were fitted to a linear and a Freundlich isotherm models.

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Alcohol sulfates (AS), alcohol ethoxysulfates (AES), linear alkyl benzenesulfonates (LAS) and methyl ester sulfonates (MES) are anionic surfactants that are widely used in household detergents and consumer products resulting in over 1 million tons being disposed of down the drain annually in the US. A monitoring campaign was conducted which collected grab effluent samples from 44 wastewater treatment plants (WWTPs) across the US to generate statistical distributions of effluent concentrations for anionic surfactants. The mean concentrations for AS, AES, LAS and MES were 5.

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Surfactants are a commercially important group of chemicals widely used on a global scale. Despite high removal efficiencies during wastewater treatment, their high consumption volumes mean that a certain fraction will always enter aquatic ecosystems, with marine environments being the ultimate sites of deposition. Consequently, surfactants have been detected within marine waters and sediments.

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