Nano-titania (n-TiO), due to its unique photocatalytic and hydrophobic properties, can be used to prepare self-cleaning cement-based smart building materials. The n-TiO degrades organic and inorganic pollutants through its photocatalytic action and convert them into non-toxic byproducts, i.e., improves the air quality. In this review, aspects such as methodologies of n-TiO synthesis, approaches for n-TiO loading on cementitious materials, photocatalytic properties, self-cleaning mechanism, and application of n-TiO in cement-based materials have been overviewed. Further, the n-TiO can be used either as coatings or admixtures in pavement blocks, mortars/concrete at zebra crossings, road dividers and linings, and high rise buildings. Moreover, the implications and economic aspects of n-TiO usage in cement-based materials revealed that n-TiO increases the material cost by ~ 27%, (101 to 128.1$) in comparison to conventional building materials. Furthermore, the low-cost carbonized materials such as biochars have been suggested to be used as support of n-TiO to lower the cost and improve the remediation efficiency of photocatalytic concrete.
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http://dx.doi.org/10.1007/s11356-021-14189-7 | DOI Listing |
Sci Total Environ
December 2024
State Key Laboratory of Freshwater Ecology and Biotechnology, Institute of Hydrobiology, Chinese Academy of Sciences, Wuhan 430072, China.
The physicochemical characteristics of titanium dioxide nanoparticles (n-TiO) may change during the aging process once discharged into aquatic environment. However, how the aging process affects their interactions with co-existing pollutants, as well as the joint toxicity has not been explored. This study investigated how UV-aging impacts n-TiO in aquatic environments and their interactions with bis(2-ethylhexyl)-2,3,4,5-tetrabromophthalate (TBPH), focusing on their joint toxicity in adult female zebrafish.
View Article and Find Full Text PDFOdontology
December 2024
Department of Restorative Dentistry, Piracicaba Dental School, University of Campinas (UNICAMP), Avenida Limeira, 901, Bairro Areião, Piracicaba, SP, Brazil.
This study evaluated the surface roughness, color change, and antibacterial effect of a ceramic glaze enhanced with TiO nanotubes (n-TiO). n-TiO (0, 2, 2.5, and 5 wt%) was added to a ceramic glaze powder, applied to the surface of forty feldspathic ceramic specimens, and sintered.
View Article and Find Full Text PDFPhys Chem Chem Phys
December 2024
Univ. Artois, CNRS, Centrale Lille, Univ. Lille, UMR 8181, Unité de Catalyse et de Chimie du Solide (UCCS), F-62300 Lens, France.
The effects of biaxial tensile and compressive strain on the structural, electronic, and photocatalytic properties of tetragonal [001] (SnO)/(TiO) superlattices have been theoretically explored using density functional theory (DFT) calculations. Various stacking periodicities between SnO layers and TiO layers, including ( = ), (, 1), and (1, ) were studied in the context of water splitting for hydrogen production. The results reveal that the (1, ) stacking periodicity exhibit the highest bulk modulus, Poisson's ratio, and Debye temperature values.
View Article and Find Full Text PDFNanomaterials (Basel)
November 2024
Anhui Provincial Key Laboratory of Green Carbon Chemistry, School of Chemistry and Material Engineering, Fuyang Normal University, Fuyang 236037, China.
Inorg Chem
December 2024
College of Science and Technology, Hebei Agricultural University, Huanghua, Hebei 061100, P. R. China.
N-doped anatase/rutile TiO (AR-N/TiO) photocatalysts were prepared by combining the strategy of N-doping and in situ heterophase junction generation, which significantly enhanced the photocatalytic H generation (1.68 mmol· h·g). Under monochromatic light at 400 nm, the light exhibits an apparent quantum efficiency of 8.
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