The direct, graft-through, ring-opening metathesis polymerisation (ROMP) of unprotected DNA macromonomers is reported. By tuning the polymerisation conditions, good control is achieved, enabling the rapid and efficient synthesis of DNA-containing bottlebrush copolymers, without the need for protection of the DNA bases.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8168459 | PMC |
http://dx.doi.org/10.1039/d0cc08008j | DOI Listing |
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