In the title compound, CHBrNO, two bridged tetra-hydro-furan rings adopt envelope conformations with the O atom as the flap. The pyrrolidine ring also adopts an envelope conformation with the spiro C atom as the flap. In the crystal, the mol-ecules are linked into dimers by pairs of C-H⋯O hydrogen bonds, thus generating (18) rings. The crystal packing is dominated by H⋯H, Br⋯H, H⋯π and Br⋯π inter-actions. One of the Br atoms is disordered over two sites with occupation ratio of 0.833 (8):0.167 (8).
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8061099 | PMC |
http://dx.doi.org/10.1107/S205698902100116X | DOI Listing |
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