Two phenoxo- and cyanido-bridged one-dimensional complexes NiGdFe (1) and NiDyFe (2) have been prepared. They are the first pentacyanidoferrite-bridged heterotrimetallic complexes. Magnetic studies reveal that overall ferromagnetic interactions are present in complexes 1 and 2, and complex 2 shows single-molecule magnet (SMM) behaviour with an energy barrier of 14.8 K.
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| http://dx.doi.org/10.1039/d1dt00693b | DOI Listing |
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