The reactivity of NOBF towards silylene, disilene, germylene, stannylenes has been described. Smooth syntheses of compounds of composition [PhC(NtBu)E(= O → BF)N(SiMe), E = Si (3) and Ge (4)] were accomplished from the corresponding tetrylenes. An unusual heterocycle (10) featuring B, Sn, N, P, and O atoms was obtained from the reaction with a stannylene, while a 1,2-vicinal anti addition of fluoride was observed with a disilene (12).
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d1cc01034d | DOI Listing |
Publication Analysis
Top Keywords
reactivity nobf
8
nobf silylene
8
silylene disilene
8
disilene germylene
8
diverse reactivity
4
germylene stannylene
4
stannylene reactivity
4
germylene stannylenes
4
stannylenes described
4
described smooth
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!