The introduction of a pyrrole ring at one of the meso positions of carbazole-based porphyrins lowers the structural symmetry and results in dual emission, which strongly depends on the excitation wavelength and temperature. The origin of dual emission induced by NH-tautomerism is confirmed via photophysical and DFT calculations.

Download full-text PDF

Source
http://dx.doi.org/10.1039/d1cc00868dDOI Listing

Publication Analysis

Top Keywords

dual emission
12
double intramolecular
4
intramolecular hydrogen
4
hydrogen transfer
4
transfer assisted
4
assisted dual
4
emission carbazole-embedded
4
carbazole-embedded porphyrin-like
4
porphyrin-like macrocycle
4
macrocycle introduction
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!