Carbon nanostructures have been recently applied to improve industrial manufacturing processes and other materials; such is the case for lubricants used in the metal-mechanic industry. Nanotori are toroidal carbon nanostructures, obtained from chemical treatment of multi-wall carbon nanotubes (MWCNTs). This material has been shown to have superb anti-wear and friction reduction performance, having the ability to homogeneously disperse within water in concentrations between 1-2 wt.%. Obtained results of these novel nanostructures under water mixtures and novel additives were a set point to our studies in different industrial lubricants. In the present work, nanotori structures have been applied in various filler fractions as reinforcement to evaluate the behavior in thermal transport of water-based (WB) and oil-based (OB) lubricants. Temperature-dependent experiments to evaluate the thermal conductivity were performed using a thermal water bath ranging from room temperature up to 323 K. The obtained results showed a highly effective and favorable improvement in the heat transport of both lubricants; oil-based results were better than water-based results, with nanotori structures increasing the lubricants' thermal transport properties by 70%, compared to pure lubricant.
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http://dx.doi.org/10.3390/nano11051158 | DOI Listing |
J Am Chem Soc
September 2024
State Key Laboratory of Elemento-Organic Chemistry, Tianjin Key Lab for Rare Earth Materials and Applications, School of Materials Science and Engineering, Nankai University, Tianjin 300350, China.
Pure-element cyclic molecules have garnered extensive attention owing to their intriguing structures and promising applications. Among these, carbon-based cyclic molecules such as []carbon (C, = 10-26) and carbon nanotori have ignited significant interest in both experimental and theoretical investigations. However, systematic investigations of analogous cyclic counterparts of heavier main-group elements are limited, with only a few known by theoretical studies.
View Article and Find Full Text PDFJ Phys Condens Matter
January 2022
Gazprom Transgaz Tomsk LLC, Russia.
The potential of tori interactions, simple in form, is obtained, which underlies the mechanisms of the formation of molecular associations in liquid crystals. In the considered linear aggregates, the short-range interactions of the tori are calculated. The dynamic state of a hexagonal tori cord is also considered.
View Article and Find Full Text PDFNanomaterials (Basel)
April 2021
Facultad de Ciencias Biológicas, Universidad Autónoma de Nuevo León, San Nicolás de los Garza 66455, NL, Mexico.
Carbon nanostructures have been recently applied to improve industrial manufacturing processes and other materials; such is the case for lubricants used in the metal-mechanic industry. Nanotori are toroidal carbon nanostructures, obtained from chemical treatment of multi-wall carbon nanotubes (MWCNTs). This material has been shown to have superb anti-wear and friction reduction performance, having the ability to homogeneously disperse within water in concentrations between 1-2 wt.
View Article and Find Full Text PDFJ Mol Model
July 2019
Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito exterior s/n, Ciudad Universitaria, Coyoacán, 04510, Ciudad de México, Mexico.
New organometallic complexes of carbon nanotori were designed and theoretically described by means of density functional theory. After a systematic structural search, it was found that energetically favorable complexes were formed by the metal atoms Cr and Ni, both located at the center of a nanotorus with diameter around 5 Å and 120 carbon atoms. The nature of the metal-nanotorus interaction shows a partial polar-covalent character, different from those found in other well-known organometallic compounds.
View Article and Find Full Text PDFChem Asian J
November 2018
Department of Chemistry, School of Chemical Science and Technology, Dr. Harisingh Gour Central University, Sagar, MP, 470003, India.
We report the formation of gold nanoparticle (AuNP)-biotinylated triskelion peptide hybrid nanostructures. These structures were created by using self-organization and mimicking strategies to develop AuNP-ornamented peptide nanobangles with predetermined properties on biocompatible surfaces. Such intelligent and fascinating nanomaterials can be used for several bio-nanotechnological applications.
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