In the title mol-ecular salt, (CHN)[CoCl], the complete dication is generated by crystallographic inversion symmetry and the piperazine ring adopts a chair conformation with the pendant methyl groups in equatorial orientations. The complete dianion is generated by crystallographic twofold symmetry. In the crystal, the (CHN) and [CoCl] ions are linked by N-H⋯Cl and C-H⋯Cl hydrogen bonds, thereby forming a two-dimensional supra-molecular network. The Hirshfeld surface analysis and fingerprint plots reveal that the largest contributions to the crystal stability come from H⋯Cl/Cl⋯H (68.4%) and H⋯H (27.4%) contacts.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8025852 | PMC |
| http://dx.doi.org/10.1107/S2056989021002954 | DOI Listing |
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