Crystallographic characterization of (CHSiMe)U(BH).

Acta Crystallogr E Crystallogr Commun

Department of Chemistry, University of California, Irvine, California 92697, USA.

Published: April 2021

New syntheses have been developed for the synthesis of (borohydrido-κ )tris-[η-(tri-methyl-sil-yl)cyclo-penta-dien-yl]uranium(IV), [U(BH)(CHSi)] or Cp'U(BH) (Cp' = CHSiMe) and its structure has been determined by single-crystal X-ray crystallography. This compound crystallized in the space group and the structure features three -coordinated Cp' rings and a -coordinated (BH) ligand.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8025856PMC
http://dx.doi.org/10.1107/S2056989021002425DOI Listing

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