The purpose of the in vitro study presented in this paper was to determine the long-term release of fluoride ions from selected ormocer materials (Admira (A), Admira Flow (AF), Admira Seal (AS)). The release of fluoride ions from these materials into a saline solution (0.9% NaCl) and deionized water was tested for 14 weeks. In a long-term study the measurements were taken after 1 and 3 h, then 1, 2, and 3 days and then at weekly intervals for 14 weeks. In a short-term study the measurements were made after 3, 24, 48, 72, 69, 168 h, i.e., within 7 days. All materials used in the test showed a constant level of fluoride release. The highest level of cumulative release of fluoride ions into deionized water was found in the AS material (23.95 ± 4.30 μg/mm), slightly lower in the A material (23.26 ± 4.16 μg/mm) and the lowest in the AF material (16.79 ± 2.26 μg/mm). The highest level of cumulative release into saline solution was found in AF (8.08 ± 1.30 μg/mm), slightly lower in AS (7.36 ± 0.30 μg/mm) and the lowest in A (6.73 ± 1.10 μg /mm). After 1 h of immersion of the samples in the saline solution, the highest level of fluoride was released by AF (0.57 ± 0.06 μg/mm) followed by A (0.20 ± 0.03 μg/mm) and AS (0.19 ± 0.02 µg/mm). Moreover, in the 14-week study, the total amount of fluoride release into the saline, which imitates the environment of the oral cavity, was observed as the highest in the AF sample.
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http://dx.doi.org/10.3390/ma14092244 | DOI Listing |
Microb Biotechnol
December 2024
Department of Biochemistry, Molecular Biology and Biophysics and Biotechnology Institute, University of Minnesota, Twin Cities, USA.
A major factor limiting the biodegradation of organofluorine compounds has been highlighted as fluoride anion toxicity produced by defluorinating enzymes. Here, two highly active defluorinases with different activities were constitutively expressed in Pseudomonas putida ATCC 12633 to examine adaption to fluoride stress. Each strain was grown on α-fluorophenylacetic acid as the sole carbon source via defluorination to mandelic acid, and each showed immediate fluoride release and delayed growth.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
December 2024
Center for Transport Technologies, Battery Technologies, AIT Austrian Institute of Technology GmbH, Giefinggasse 2, Vienna 1210, Austria.
In this work, a battery layup consisting of a poorly flammable ionic liquid electrolyte and a poly(vinylidene fluoride--hexafluoropropylene) (PVdF-HFP) thermoplastic has been developed along with composite anode and cathode electrodes. The developed gel electrolyte exhibits feasible ionic conductivity of about 1 mS/cm at 30 °C. State-of-the-art active electrode materials, i.
View Article and Find Full Text PDFMaterials (Basel)
November 2024
Department of Epidemiology and Public Health, Tokyo Dental College, Tokyo 101-0061, Japan.
An intraoral fluoride-releasing device (IFRD) is a cost-effective tool for introducing fluoride into the oral cavity. It allows prolonged uptake of low concentrations of fluoride into teeth. We developed a new IFRD using 3D additive manufacturing and a new low-release fluoride gel.
View Article and Find Full Text PDFSci Total Environ
December 2024
Department of Chemistry and Environmental Science, New Jersey Institute of Technology, Newark, NJ, United States. Electronic address:
Fluorotelomer carboxylic acids (FTCAs) has drawn increasing attention due to their prevalent occurrence, high toxicity, and bioaccumulating effects. In this study, microbial consortia with sustainable FTCA removal abilities were enriched and characterized from two activated sludges and five soils when no external carbon sources were supplemented. After four generations of enrichment, stable 6:2 FTCA and 5:3 FTCA biodegradation were achieved, reaching 0.
View Article and Find Full Text PDFLangmuir
December 2024
Graduate School of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510, Japan.
In biological systems, various stimuli and energies are transduced into membrane potentials via ion transport or binding. The application of this concept to artificial devices may result in biomimetic signal transmitters and energy harvesters. In this study, we investigated the mechanical control of fluoride anion recognition with naphthalenediimide (NDI) monolayers at the air-water interface.
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