AI Article Synopsis

  • A new coordination compound of copper and tiglic acid, called tetrakis(μ-tiglato)bis(tiglic acid)dicopper(II), was synthesized and its structure analyzed using X-ray diffraction.
  • The compound features a paddle-wheel coordination system, and its structural attributes were compared to other known copper coordination compounds.
  • Detailed analyses, including Hirshfeld analysis and characterization of infrared absorption, thermal, and magnetic properties, revealed that the copper ions exhibit antiferromagnetic coupling.

Article Abstract

The first coordination compound of copper and tiglic acid named tetrakis(μ-tiglato)bis(tiglic acid)dicopper(II) was synthesized and crystallized from water solution. Its structure was determined and analyzed based on X-ray diffraction measurement. The paddle-wheel coordination system of the investigated compound was compared with other similar copper structures known in the literature. The Hirshfeld analysis was used for the detailed analysis of intermolecular interaction. The new compound was also characterized in terms of infrared absorption, thermal, and magnetic properties. The antiferromagnetic coupling of copper ions was found.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8122876PMC
http://dx.doi.org/10.3390/ma14092148DOI Listing

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