The stoichiometric reaction of -[Pd(ITMe)(SiR)], where (SiR = SiMe and SiMePh and ITMe = 1,3,4,5-tetramethylimidazol-2-ylidene) with allyl bromide affords the corresponding allylsilanes along with complexes of the type -[Pd(ITMe)(SiR)(Br)]. The structure of -[Pd(ITMe)(SiMePh)Br] has been determined in the solid state and displays a slightly distorted square-planar geometry with the two N-heterocyclic carbene ligands in a -configuration.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8122886 | PMC |
| http://dx.doi.org/10.3390/molecules26092460 | DOI Listing |
Publication Analysis
Top Keywords
synthesis -monosilylpalladiumii
4
-monosilylpalladiumii bromide
4
bromide complexes
4
complexes stoichiometric
4
stoichiometric reaction
4
reaction -[pditmesir]
4
-[pditmesir] sir
4
sir sime
4
sime simeph
4
simeph itme
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!