In this study, we have synthesized B doped Ca5(PO4)3OH (HAP) by a sonication chemical method. The thermoluminescence (TL) properties of the family of synthesized samples (B doped Ca5(PO4)3OH (HAP) were investigated using an IRSL-TL 565 nm filter. This gave the highest TL intensity of each phosphor after 2 Gy β-irradiation. Three TL glow peaks of B doped Ca5(PO4)3OH (HAP) are centered at around 84, 208 and 324 °C (with a heating rate of 2 °Cs-1). The trapping parameters such as activation energy (E), order of kinetics (b), frequency factor (s) were calculated by using initial rise (IR), various heating rates (VHR) and computerized glow curve deconvolution (CGCD) method. The response of TL glow curves remained constant within ±5% deviation from the initial value after 9 cycles of reuse; but only at tenth cycle the deviation goes up to 6%.
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http://dx.doi.org/10.1016/j.apradiso.2021.109738 | DOI Listing |
Appl Radiat Isot
July 2021
Physics Department, Jazan University, P.O. Box 114, 45142, Jazan, Saudi Arabia; Department of Physics, Manisa Celal Bayar University, Faculty of Arts and Sciences, Muradiye-Manisa, 45010, Turkey. Electronic address:
In this study, we have synthesized B doped Ca5(PO4)3OH (HAP) by a sonication chemical method. The thermoluminescence (TL) properties of the family of synthesized samples (B doped Ca5(PO4)3OH (HAP) were investigated using an IRSL-TL 565 nm filter. This gave the highest TL intensity of each phosphor after 2 Gy β-irradiation.
View Article and Find Full Text PDFInorg Chem
October 2019
Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education of China) and Key Laboratory of Sustainable Resources Processing and Advanced Materials of Hunan Province College , Hunan Normal University, Changsha 410081 , China.
Photoluminescence quantum efficiency (QE) and thermal stability are important for phosphors used in phosphor-converted light-emitting diodes (pc-LEDs). Hydroxyapatite, Ca(PO)OH, is generally not used as host for phosphors, because the OH group in the host will lead to a high vibrational frequency around the activators and reduces the luminescent efficiency or even quenches the emission. In this work, strong blue emission at 450 nm appears after introducing boron atoms into Ce-doped hydroxyapatite under excitation of a UV light.
View Article and Find Full Text PDFMater Sci Eng C Mater Biol Appl
December 2014
School of Materials Science and Engineering, Shandong University of Technology, 255049 Shandong, PR China.
An in situ hydrothermal crystallization method with presence of glutamic acid, urea and yttrium ions was employed to fabricate hexagonal hydroxyapatite (HAp, Ca5(PO4)3(OH)) tubes with length of 200 nm-1 μm. Firstly, yttrium ion-doped HAp (Y-HAp, Ca(5-x)Y(x)(PO4)3(OH)) was synthesized after hydrolysis of urea and HPO4(2-) ions at 100°C with a dwell time of 24h. The shift of X-ray diffraction peaks of HAp to high angle was caused the substitution of Ca(2+) ions by small-sized Y(3+) ions.
View Article and Find Full Text PDFBiomaterials
June 2005
Department of Physics, Queen's University, Stirling Hall, Queen's Crescent, Kingston, Ont., Canada, K7 3P6.
The sintering of silicon doped calcium phosphate ceramics prepared from a basic colloidal hydroxyapatite (Ca5(PO4)3OH or HA) precipitate mixed with silica over 800 degrees C yields a phase mixture of tricalcium phosphate phases (TCP) designated Si-TCP, beta-TCP and a silicon substituted dehydrated apatite (Si-Ap). The Si-TCP phase is defined as a combination of a silicon stabilized TCP in which the silicon content attains a saturated value (Ca3(P0.9Si0.
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