The safe disposal of municipal solid waste incineration fly ash (MSWIFA) has become the weakest link of the circular economy of MSW due to its hazardous nature. In this study, we focused on the heavy metals solidification of MSWIFA by using alkali-activation technology and introducing a mold-pressing method. The influence of alkaline activator (AA) including alkali concentration and dosage of sodium silicate solution were well designed and studied. MSWIFA before and after alkali-activation, as well as the sample treated by commercial chelating agent (CA), were contrastively studied the performance of heavy metals solidification. The results show that the alkali-activated MSWIFA exhibits superior solidification for heavy metals than the blank control and the CA treated ones. With mold-pressing technology, the alkali-activated MSWIFA shows a core-shell structure, in which a thin layer that is composed of mainly N-A-S-H gel is as the shell and acts as a protective layer to inhibit the leaching of heavy metals. Besides, the introduced mold-pressing technology is beneficial for the improvement of materials strength and the reduction of AA dosage. The optimal AA composition is that the net concentration of NaOH is ∼4 M and sodium silicate dosage is ∼65 wt% in alkaline activator, and the total alkaline activator requirement is only 32 wt% of MSWIFA, yielding 7.9 MPa compressive strength at 10.2 MPa molding pressure. In summary, this work paves a potential new way for safe and recycling use of hazardous MSWIFA, which will be of great significance to environmental sustainability.
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http://dx.doi.org/10.1016/j.wasman.2021.04.003 | DOI Listing |
Environ Monit Assess
January 2025
School of Metallurgy and Environment, Central South University, Changsha, 410083, Hunan, China.
In this study, an efficient membrane composed of polysulfone and graphene oxide was developed and evaluated for its efficacy in chromium adsorption. Characterization of the synthesized membrane involved comprehensive analyses including scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA) and Fourier-transform infrared spectroscopy (FTIR) to assess its structural properties. Subsequently, the membrane's performance in removing chromium from aqueous solutions was scrutinized, considering key operational parameters.
View Article and Find Full Text PDFMicrobiology (Reading)
January 2025
Department of Biology, Tor Vergata University of Rome, Rome, Italy.
Nutritional immunity, a key component of the vertebrate innate immune response, involves the modulation of zinc availability to limit the growth of pathogens. counteracts host-imposed zinc starvation through metabolic adaptations, including reprogramming of gene expression and activating efficient metal uptake systems. To unravel how zinc shortage contributes to the complexity of bacterial adaptation to the host environment, it is critical to use model systems that mimic fundamental features of -related diseases in humans.
View Article and Find Full Text PDFHua Xi Kou Qiang Yi Xue Za Zhi
February 2025
Center of Stomatology, Peking University Shenzhen Hospital, Shenzhen 518036, China.
Objectives: This study aims to explore the effect of improving clinical efficiency by replacing traditional impression workflow with centralized digital impression workflow.
Methods: The department of prosthodontics in Center of Stomatology, Peking University Shenzhen Hospital has improved the clinical workflow by replacing the traditional impression made by doctors using impression materials for each patient with a centralized digital impression made by one technician for all patients in the department. This cross-sectional study recorded the chairside time required for impression taking in patients undergoing single posterior zirconia full crown restoration before clinical process improvement; the time required for centralized digital impression production; the comfort level of patients; and the adjacency relationship, occlusal contact relationship, and time required for prostheses adjusting (i.
F1000Res
January 2025
Doctorado en Medicina Tropical, Faculty of Medicine, Universidad de Cartagena, Cartagena, Bolívar, Colombia.
Background: Contamination of Cartagena Bay, Colombia with heavy metals such as mercury (Hg) and cadmium (Cd) presents a major environmental and public health concern, particularly for human communities residing on nearby islands and coastal areas. These populations face enhanced exposure risks owing to their traditional fishing practices and continuous interactions with polluted marine environments. This study aimed to evaluate the genotoxic effects of environmental exposure to Hg and Cd in populations from the island zone of the Cartagena district, Bolívar.
View Article and Find Full Text PDFFront Public Health
January 2025
Department of General Surgery, The First Affiliated Hospital, Jiamusi University, Jiamusi, China.
Background: Metabolic-associated steatohepatitis and liver fibrosis (MASLD) is a growing public health concern, with environmental factors potentially playing a role in its development. This study aimed to investigate the associations between serum cadmium and mercury levels and the risk of MASLD in a nationally representative sample from the United States.
Methods: Data from the National Health and Nutrition Examination Survey from 1999 to 2018 were analyzed.
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