The thermodynamic (PCN-222) and kinetic (PCN-224) products of porphyrinic Zr-metal-organic frameworks (MOFs) were synthesized via an anodic dissolution approach for the first time. To the best of our knowledge, this is the first report of MOF polymorphs being controlled by electrolysis. The selective formation of PCN-222 requires an amorphous component to be present on the electrode during the initial reaction process.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d1dt00491c | DOI Listing |
Publication Analysis
Top Keywords
porphyrinic zr-metal-organic
8
zr-metal-organic frameworks
8
electrolytic synthesis
4
synthesis porphyrinic
4
frameworks selective
4
selective crystal
4
crystal topologies
4
topologies thermodynamic
4
thermodynamic pcn-222
4
pcn-222 kinetic
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!