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Palladium-Catalyzed Sulfinylation of Aryl- and Alkenylborons with Sulfinate Esters. | LitMetric
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Palladium-Catalyzed Sulfinylation of Aryl- and Alkenylborons with Sulfinate Esters.

Minori Suzuki Kazuya Kanemoto Yu Nakamura Takamitsu Hosoya Suguru Yoshida

Org Lett

Laboratory of Chemical Bioscience, Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University (TMDU), 2-3-10 Kanda-Surugadai, Chiyoda-ku, Tokyo 101-0062, Japan.

Published: May 2021

An efficient, direct sulfinylation of organoborons catalyzed by palladium is disclosed. Treatment of organoborons and sulfinate esters in the presence of a palladium precatalyst provided a broad range of sulfoxides. Various organosulfur compounds having oxidizable functional groups were successfully prepared through the sulfoxide synthesis.

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 Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8289295PMC
http://dx.doi.org/10.1021/acs.orglett.1c01292DOI Listing

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