A non-isolated pentagon rule C cage stabilized by a stretched ScN cluster.

Chem Commun (Camb)

College of Chemistry, Chemical Engineering and Materials Science, and State Key Laboratory of Radiation Medicine and Protection, Soochow University, Suzhou, Jiangsu 215123, P. R. China.

Published: April 2021

A novel cluster fullerene, Sc3N@Cs(39 663)-C82, has been synthesized and characterized. Crystallograpic charaterization unambiguously determines the non-IPR cage structure of Cs(39 663)-C82. Structural analyses further reveal that the Sc3N cluster is notably stretched to facilitate the interaction with the non-IPR fullerene cage.

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Source
http://dx.doi.org/10.1039/d1cc00328cDOI Listing

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