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Water binding stabilizes stacked conformations of ferrocene containing sheet-like aromatic oligoamides. | LitMetric

Water binding stabilizes stacked conformations of ferrocene containing sheet-like aromatic oligoamides.

Org Biomol Chem

Institute of Condensed Matter and Nanosciences, Université catholique de Louvain, Place Louis Pasteur 1, Louvain-la-Neuve, 1348, Belgium.

Published: June 2021

AI Article Synopsis

Article Abstract

While water clusters play an essential role in the stability of biological structures, their ability to stabilize synthetic oligomers is less understood. We have synthesized a heptameric sheet-like aromatic oligoamide foldamer with ferrocene as turn unit. It shows strong interactions with water in the solid state and in solution. The water binding limits the fluxional processes resulting from the flexible ferrocene unit, highlighting the importance of such interactions for conformational studies on this class of molecule.

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Source
http://dx.doi.org/10.1039/d1ob00580dDOI Listing

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