Pd/Ni → Ge-F interactions supported by phosphine-chelation were found to trigger dual activation of Ge-F bonds under mild conditions. This makes fluoro germanes suitable partners for catalytic Ge-C cross-coupling and enables Germa-Suzuki reactions to be achieved for the first time.
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| http://dx.doi.org/10.1039/d1cc01392k | DOI Listing |
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