Atomic layer deposition (ALD) is a promising method for preparing nanomaterials. The thickness and uniformity of nanomaterials can be precisely controlled. Hence, the uniform Ni nanoparticles (Ni NPs) deposited on reduced graphene oxide (rGO) by ALD and got the optimal combination interface. The morphology, structure, and electrochemical behavior of Ni NPs-rGO nanocomposite are investigated. By experiment results, the Ni NPs could occupy some active surface of rGO, resulting in high conductivity and large specific surface area of Ni NPs-rGO nanocomposite. The Ni NPs-rGO nanocomposite exhibits high electrocatalytic activity for serotonin and speeds up the electron transfer between the surface of the electrode and the solution. Therefore, the sensor is prepared by Ni NPs-rGO nanocomposite modified glassy carbon electrode (GCE) and used to sensitive detection of serotonin. By differential pulse voltammetric, the Ni NPs-rGO/GCE enhanced the current responses and showed a wide linear range of 0.02-2 μM with a low detection of 0.01 μM for serotonin (S/N = 3). The Ni NPs-rGO/GCE exhibited good stability, selectivity, and anti-interference ability that can be used for real sample detection. According to these results, the Ni NPs-rGO nanocompositeis successfully prepared by ALD. The properties of Ni NPs-rGO nanocomposite make it an attractive material for potential applications in sensors and catalysis.
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http://dx.doi.org/10.1016/j.bioelechem.2021.107820 | DOI Listing |
Mikrochim Acta
July 2024
Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei Key Laboratory of Polymer Materials, School of Materials Science and Engineering, Hubei University, Wuhan, 430062, China.
ACS Omega
January 2023
Department of Chemistry, Shivaji University, Kolhapur416 004, Maharashtra, India.
The binary as well as ternary nanocomposites of the square-facet nanobar Co-MOF-derived CoO@Co/N-CNTs (N-CNTs: nitrogen-doped carbon nanotubes) with Ag NPs and rGO have been synthesized via an easy wet chemical route, and their supercapacitor behavior was then studied. At a controlled pH of the precursor solution, square-facet nanobars of Co-MOF were first synthesized by the solvothermal method and then pyrolyzed under a controlled nitrogen atmosphere to get a core-shell system of CoO@Co/N-CNTs. In the second step, different compositions of CoO@Co/N-CNT core-shell structures were formed by an method with Ag NPs and rGO moieties.
View Article and Find Full Text PDFJ Mater Chem B
January 2023
State Key Laboratory of Food Science and Technology, Jiangnan University, No. 1800 Lihu Avenue, Wuxi, Jiangsu, 214122, P. R. China.
Fluorescent gold (Au) nanostructures have emerged as burgeoning materials to fabricate nanomaterial assemblies which play a vital role in improving the detection sensitivity and specificity for various biomolecules. In this work, a fluorescence labelled (Rhodamine-B-Isothiocyanate) silica shell with Au metal core (AuNPs@PVP@RITC@SiO) and a graphene-Au nanostar nanocomposite (rGO-AuNS) are presented as a metal enhanced fluorescence (MEF) material and Raman signal enhancer, respectively. Their composite (AuNPs@PVP@RITC@SiONPs/rGO-AuNS) was employed as a dual-mode fluorescence (FL) and surface-enhanced Raman scattering (SERS) nanoprobe for selective and sensitive detection of T-2 toxin.
View Article and Find Full Text PDFBioelectrochemistry
August 2021
Key Laboratory of Water Environment Evolution and Pollution Control in Three Gorges Reservoir, Chongqing Three Gorges University, Wanzhou 404100, PR China.
Atomic layer deposition (ALD) is a promising method for preparing nanomaterials. The thickness and uniformity of nanomaterials can be precisely controlled. Hence, the uniform Ni nanoparticles (Ni NPs) deposited on reduced graphene oxide (rGO) by ALD and got the optimal combination interface.
View Article and Find Full Text PDFMicrochem J
May 2021
Department of Pharmaceutical Analytical Chemistry, Faculty of Pharmacy, Assiut University, Assiut, Egypt.
In this study, zinc sulfide nanoparticles were loaded on reduced graphene oxide (ZnS NPs/rGO) using simple sonochemical method. The nanocomposite was characterized using different morphological and electrochemical techniques such as TEM, SEM, PXRD, EDX, Raman spectroscopy, FTIR, N-adsorption-desorption, CV, and EIS. The ZnS NPs/rGO modified glassy carbon electrode (GCE) was used to simultaneously estimate hydroxychloroquine (HCQ) and daclatasvir (DAC) in a binary mixture for the first time.
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